Rates of Reaction (Paper 2) Flashcards

(65 cards)

1
Q

What is meant by rate of reaction

A

How quickly reactants turn into products

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2
Q

Phrase used to describe how quickly reactants turn into products

A

Rate of reaction

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3
Q

2 things to measure when calculating rate of reaction

A

How quickly the reactant is used up
How quickly the product is produced

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4
Q

True or false, some reactions can take years or decades

A

True (e.g rusting of iron)

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5
Q

True or false, some reactions take place in just a fraction of a second

A

True e.g fireworks

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6
Q

Equation to measure how fast the reactants are being used up (rate of reaction)

A

Quantity of reactants used/ time taken

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7
Q

Measuring how quickly the reactant is used up/ how quickly the product Is formed are 2 different ways to tell you the…

A

Rate of reaction

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8
Q

Equation to measure how quickly the product is formed (rate of reaction)

A

Quantity of product formed/ time taken

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9
Q

When measuring rate of reaction, what is the quantity (of reactant/ product) measured in

A

Grams or cm cubed

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10
Q

When measuring rate of reaction, what is time taken measured in

A

Seconds

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11
Q

Do reactions start of fast and slow down or slow and speed up

A

Start fast but slow down
(That’s why when measuring rate of reaction it’s only an average)

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12
Q

When drawing graphs showing rate of reaction, what goes on the x axis

A

Time (in seconds)

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13
Q

When drawing graphs showing rate of reaction what goes on the y axis

A

Mass of reactant used/ product formed (g or cm cubed)

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14
Q

5 factors affecting rate of reaction

A

Surface area
Temperature
Concentration
(Absence/ presence of) catalyst
Pressure of gases

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15
Q

What is meant by collision theory

A

In order to react, particles must collide with sufficient energy

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16
Q

Name for theory where in order to react, particles must collide with sufficient energy

A

Collision theory

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17
Q

The collision theory states that in order to… particles must…with sufficient…

A

React, collide, energy

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18
Q

Name for minimum amount of energy needed for particles to collide with each other and react

A

Activation energy

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19
Q

What is activation energy

A

Minimum amount of energy needed for particles to collide with each other and react

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20
Q

How temperature increases rate of reaction

A

As temperature increases, particles gain more kinetic energy and move faster so there are more frequent collisions and they will collide with more energy so more of the collisions are successful

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21
Q

Both concentration and pressure refer to how many particles there are per unit of…

A

Volume

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22
Q

How increasing pressure/ concentration increases rate of reaction

A

Increasing pressure/ concentration means that there are more particles per unit of volume so more frequent collisions which increases rate of reaction

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23
Q

How increasing surface area increases rate of reaction

A

The greater the surface area, the more particles there are that are exposed, so more frequent collisions which increases rate of reaction

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24
Q

What is a catalyst

A

Something that speeds up the rate of reaction without being used up

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25
Why aren't catalysts used in the reaction equation
They aren't reactants or products
26
What do catalysts do to the activation energy
Lower it (Particles need less energy to collide and react)
27
A catalyst provides an alternative... which lowers the activation energy reaction
Pathway
28
How to calculate rate of reaction at a particular time using graph
Draw tangent at particular time you're interested in and measure gradient
29
When writing an equation what does the double arrow mean
The reaction is reversible
30
How to represent reaction being reversible when writing an equation
Use double arrow (not single one)
31
In a reversible reaction we call the top arrow the... reaction
Forward
32
In a reversible reaction we call the bottom arrow the... reaction
Backward
33
True or false, in a reversible reaction both the forward and backward reaction can happen
True
34
True or false, in a reversible reaction the forward and backward reactions can take place at different rates
True
35
Dynamic equilibrium meaning
Point in reversible reaction where the forward and backward reaction are at the same rate in a closed system (Both reactions are happening but they basically cancel each other out)
36
True or false, in dynamic equilibrium the amount of reactant and product are always equal
False They are always constant but not necessarily the same as each other
37
Equilibrium can only be reached if the reaction is done in what type of system
Closed system
38
True or false, in a closed system no reactants or products can escape
True
39
True or false, at equilibrium the reactants are still turning into products and products still turning back into reactants
True- it's just at the same rate so the amount of reactants and products are constant (not necessarily equal)
40
True or false, equilibrium can only be reached if the reaction is done in a closed system
True Otherwise the reactants/ products could keep escaping
41
True or false, reversible reactions are always exothermic in one direction and endothermic in the other direction
True
42
Hydrated meaning
Water is present
43
Anhydrous meaning
No water is present
44
True or false, the position of equilibrium can change (shift to left/ right) depending on conditions
True
45
Le Chatelier's principle is about the position of what during a reversible reaction
Equilibrium
46
3 main ways to change conditions of closed system
Temperature Pressure Concentration
47
If there are more reactants than products does the equilibrium lie to the left or right
Left
48
If there are more products than reactants does the equilibrium lie to the left or right
Right
49
Why do exothermic reactions have an overall negative energy change
Energy is released to surroundings so lost
50
Why do endothermic reactions have an overall positive energy change
Take in energy from surrounds so energy is gained (added)
51
What is a reversible reaction
Reaction where reactants can turn into products and products can turn back into reactants
52
What is meant by Le Chatelier's principle
If a change is made to a system that's at dynamic equilibrium, the system will try to undo (counteract) the change by favouring either the forward or reverse reaction so that it stays at dynamic equilibrium
53
If the concentration of the product is lowered, which reaction will the system favour and why
Forward reaction Forward reaction turns reactants into products and the way to counteract a decreased product concentration is to increase it
54
If I increase the temperature what will the system do and how
Decrease temperature Favour endothermic reaction which decreases temperature so moves towards endothermic
55
If I decrease the temperature what will the system do and how
Increase temperature by favouring (moving towards) exothermic reaction which increases temperature
56
If I increase concentration what will the system do
Decrease concentration by moving towards reaction that removes that chemical
57
If I decrease concentration what will the system do
Move towards reaction that produces that chemical
58
If I increase pressure what will the system do
Decrease pressure by favouring reaction that produces fewest molecules
59
If I decrease pressure what will the system do
Increase pressure by favouring reaction that produces greatest number of molecules
60
2 units for rate of reaction
g/s Cm cubed/ s (as the quantity of reactant used/ product formed can either be measured in grams or cm cubed and time is always in seconds)
61
5 examples of evidence for a chemical reaction occurring
Change in colour Change in temperature Bubbles/ fizzing Precipitate (solid) formed Odours/ sounds
62
What do particles do if they don't have enough energy to react
Bounce off each other
63
Why does the rate of reaction decrease towards the end
Reactants becoming used up so less frequent collisions
64
How can we tell on a graph where the rate of reaction is highest
Steepest gradient
65
If the temperature of a reversible reaction is raised, what happens to the yield from the exothermic reaction
It decreases