Unit 4 Flashcards

(45 cards)

1
Q

Double arrow sign, means it reaches the balanced point or

A

equilbrium

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2
Q

the state of a chemical reaction in which its forward and reverse reactions occur at the equal rates so that the concentrations of the reactants and products dont have the net change over time

A

chemical equilbrium

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3
Q

an equilbrium of the moving system while forwards and reverse chemical reactions still keep going

A

Dynamic equilbrium

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4
Q

states that for a reversible reaction at equilibrium, the ratio of concentrations of products vs. reactants is a constant K

A

Law of mass action

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5
Q

At equilbrium point, the mass action expression is called

A

equilbrium constant (K).

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6
Q

At non-equilbrium point, the mass action expression is called

A

quotient (Q)

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7
Q

chemical compounds involved are just in one phase

A

homogeneous equilbrium

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8
Q

chemical compounds involved are in two or more phases

A

heterogeneous equilbrium

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9
Q

List out the concentrations at Initial and Equilibrium points through the counting of concentration Change

A

ICE approach

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10
Q

Material decreases in one side of equilbrium will cause corresponding material increase on the other side according to mole ratio

A

Analysis of material balance

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11
Q

If a system at equilibrium is disturbed by a change in temp, pressure or the concentration of one of the components, the system tends to adjust to a new equilbrium that could counteract (or adapt to) the change imposed (with minimum amount of effort)

A

Le Chatelier’s Principle

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12
Q

is a substance that dissolves in water to increase the concentration of H

A

acid

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13
Q

is a substance that dissolves in water to increase the concentration of OH

A

base

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14
Q

is a substance that donates a proton H to a base

A

acid

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15
Q

is a substance that acccepts proton H from an acid

A

base

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16
Q

allows acid-base reactions to occur more than just aqueous solutions

A

Bronsted-Lowry

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17
Q

For a substance to be a proton acceptor, it must have an unshared pair of elections

A

Lewis

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18
Q

The concentration of hydrogen ions in aqueous solutions is expressed as

A

pH

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19
Q

N2(g) + 3H2(g) –> 2NH3(g)

A

Haber process

20
Q

is found by substituting reactant and product concentrations or partial pressures at any point during a reaction into the equilbrium-constant expression.

A

reactant quotient (Q)

21
Q

if often used to represent the predominant for of H+ in water instead of the simpler H+ (aq)

A

hydronium ion (H30+)

22
Q

is a substance that donates a proton to another substance

A

Bronsted-Lowry acid

23
Q

is a substance that accepts a proton from another substance

A

Bronsted-Lowry base

24
Q

one that can function as either a Broasted-Lowry acid or base, depending on the substance with which it reacts

25
formed by removing a proton from the acid
Conjugate base
26
formed by adding a proton to the base
Conjugate acid
27
only differ in the presence or absence of a proton are called
conjugate acid-base pair
28
one water molecule can donate a proton to another water molecule
autoionization
29
have more than one ionizable proton
Polyprotic acids
30
the anions of weak acids
amines
31
Kb The extent to which a weak base reacts with water to generate the corresponding conjugate acid and OH- is measured by the
base-dissociation constant
32
The reaction of ions with water, with a resultant chance in pH is called
hydrolysis
33
the same number of OH groups and the same number of O atoms, acid strength increases with increasing electronegativity of the central atom
oxyacids
34
are organic acids containing the COOH group, are the most important class of organic acids
Carboxylic acids
35
is an electron-pair accepts
Lewis acid
36
is an electron-pair donor
Lewis base
37
adding or removing a reactant or product
concentration
38
changing the pressure by changing the volume
pressure
39
for a neutral solution
pH=7
40
for an acidic solution
pH<7
41
for a basic solution
pH>7
42
7 strong acids
``` HClO4 HCl HClO3 HBr HNO3 HI H2SO4 ```
43
8 strong bases
``` LiOH NaOH KOH Ca(OH)2 RbOH Sr(OH)2 CsOH Ba(OH)2 ```
44
Kw to denote the equilibrium constant. 1.0*10^-14
ion-product constant
45
Ka is an equilibrium constant for the ionization of an acid
acid-dissociation constant