W11 Flashcards
(8 cards)
Nernst equation

Cell potential for a spontaneous reaction when given half cell potentials (in galvanic/daniel cell)
E = E(cell undergoing reduction) - E(cell undergoing oxidation)
For a spontaneous reaction, Ecell is
Positive
What are standard conditions for electrochemical cells?
- 298K
- 1M
- 1 atm
Relate gibbs free energy to cell potential
G = -nFEocell
units for gibbs free energy
kJ/mol or J/mol
Modify Nerst equation to find Kc
At equilibrium, standard electrode potential is 0
Rearrange Nerst equation: