Chemistry EMPA Written Task Flashcards

1
Q

What test would you use just to identify a simple acid?

A

Universal indicator

- result= red

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2
Q

Test for primary alcohol?

A

Reagent: acidified potassium dichromate + low temperature (to prevent further oxidation into a secondary alcohol = carboxylic acid
colour changes from orange> green (colour of reduced chronium lll ions)
OR
purple> colourless (with potassium manganate Vll)- colour of reduced manganate ll ion).

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3
Q

Test for a secondary alcohol?

A

Reagent: acidified potassium dichromate + refluxed (further oxidised) = ketone
colour changes from orange> green (colour of reduced chronium lll ions)
OR
purple> colourless (with potassium manganate Vll)- colour of reduced manganate ll ion)

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4
Q

Test for a tertiary alcohol?

A

Reagent: no visible colour change because in tertiary alcohols the carbon carrying the hydoxyl (OH) group is not bonded to any hydrogen atoms. So there are no C-H bonds to break and the C-C bonds would require too vigorous conditions to break.

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5
Q

why is starch added to bread to absorb water vapour?

A

To stop the acid reacting with the sodium hydrogencarbonate beforehand.

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6
Q

Sodium hydrogencarbonate produces CO2 in baking powder. What is the advantage of an acid?

A

The acid neutrilises/reacts with NaHCO3 to produce CO2.

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7
Q

Studies have shown tartaric acid can cause paralysis and ultimately death. Why is this not an issue in baking powder?

A

Because acid is only going to be used in small quantities in baking powder.

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8
Q

Improvements to techniques in the experiment (Section C)

A
  • Wash the rod into the flask (after stirring)
  • Wash beaker into flask (after pouring solution into flask)
  • Wash funnel into flask (after filtering through contents)
  • Shake/mix final solution.
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9
Q

How do you obtain an average titre from a titration?

A

Do further titrations to produce two concordant results

  • Add together the 2 most concordant results and divide by 2
  • exclude other results before calculating average.
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10
Q

Barium chloride is added to magnesium sulfate until no more white precipitate was formed and the mixture was filtered. What 2 main ions were involved in the filtrate?

A

Cl- (Barium chloride) and Mg2+ (Magnesium sulfate)

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11
Q

Why would you use an excess of a solution instead of a solution (reagent) instead of a solid- could be other way round

A

To ensure all the compound was reacted/

To ensure all the residue was pure (reacted)

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12
Q

To seperate two reactants where one of them is soluble?

A

add cold water and filter it out

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13
Q

When it says work out percntage by mass?

A

do mass = moles x Mr then TIMES BY !00

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14
Q

why is a solution filtered to remove soluble impurities before calculating mass?

A

it could affect the mass of a precipitate

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15
Q

why is magnesium hydroxide used instead of magneium caebonate to neutrilsie stomach acid?

A

It proudces less gas in the stomach (C02) so less wind

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16
Q

(CH3COO)2Ca decomposes to..?

A

CH3C0CH3 + CaC03 (ester>ketone it loses 2 hydrogens

17
Q

Steroisimomers?

A

Different strucutral formula but a different arrangement of atoms in space

18
Q

splittign water molecules..?

A

hydrolsis

19
Q

Acid and sodium hydroxide risks?

A

splitting and leaking irritant chemicals

20
Q

Make something stay warmer?

A

slower rate of reaction

21
Q

purpose of ant-bumping granules?

A

prevent vigorous boiling

22
Q

Why would soemthing break down slower in dark bottles?

A

light decomposes things quicker

23
Q

How would you improve an experiment to make it more accurate?

A

use a water bath-constant temperature

calimometre- reduces human reaction time

24
Q

improvements to preparations of acids?

A

rinse beaker
use stirrer
inert flask