Chemistry (Organic chemistry) Flashcards

1
Q

Homologous series is?

A

same functional group

same structural formuala

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2
Q

definitions for structural formula and displayed formula?

A

displayed- shows every atom and every bond

structural formula- shows a simpied version of all the ome

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3
Q

suffix/prefix and functional group for all molecules?

A

alkenes- C=C, CnH2n
alkanes- C-C, CnH2n+2
alcohols- 0-H, CnH2n+1 (end with -ol ALWAYS)
esters- Ch3-C=0 (oate)
aldehydes- H-C=0 (ends with -al)/ (starts with hydroxy)
ketones- C=0 (end with one/starts with oxo- No number positions
IF KETONE AND ALDEHYDE OR ALCOHOL IN SAME MOLECULE ADLEHYDE?ALCOHOL TAKES PRIOTIRTY
STARTS WITH OXO
Carboxylic acid- COOH-C=0

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4
Q

Naming organic comounds?

A

carboh longest chain- meth, eyth,prop, but
identify funcitonal group(s)
If not an alkane, idnetify shortest number to functional group
Idenitfy other gorups e.g. methyl groups, halogen atoms

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5
Q

If halogen atoms..?

A

alphabetical, doesn’t matter if number order isnt right

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6
Q

naming methyl groups?

A

methyl- CH3
ethyl - CH3CH2
Propyl- CH3CH2CH2
Butyl- CH3CH2CH2CH2

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7
Q

How many hydrogens shoukld it have when you star adding groups?

A

add CH3 - need to take away 1 hydorgen and add 3 (should be two more thanorigial chain -CHECK WHETHER ALKANE OR ALKENE)
add CH3CH2- need to take away 1 +2+2
Alcohol- take away 1 and add one (number should stay the same)
haloalkane- 1 less hydrogen

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8
Q

Only after propene can alkanes start..?

A

having a number position for the functional group of C=C

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9
Q

Alkanes can either be straight-chained or ?

A

branched chain- pack less closely together

less bond enthalpy (energy to break)

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10
Q

How does the m.p//b.p change with change length?

A

icreases-more Van der Waala forced

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11
Q

Isomersism means?

A

same molecular formulka (number of atoms) but differnt diplayed and strucutural formula

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12
Q

Differnt types of isomers?

A

geometric isomers- JUST FOR ALKANES

strucutral isomers

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13
Q

What are structural isomers?

A

positional iosomerism- functional group is another place e.g but-1-ene and but-2-eme
Functional group isomerism- fucntional group changes e.g. alcohol>ester
Chian isomer-s hydrocarbon chain changes to make branches/chains
e.g. butane>2-methyl-propane

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