AAMC FL3 C/P Flashcards

1
Q

Doppler equation

A
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2
Q

if someone is moving towards a stationary sound source, how doe the perceived frequency change

A

frequency is increases because (v + vo) / v > 1

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3
Q

if someone is moving away from a stationary sound source, how does the perceived frequency change

A

frequency decreases because (v - vo) / v < 1

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4
Q

if a sound source is moving towards a stationary person, how does the perceived frequency change

A

frequency increases because v / (v - vs) > 1

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5
Q

if a sound source is moving away from a stationary person, how does the perceived frequency change

A

frequency decreases because v / (v + vs) < 1

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6
Q

1 joule =

A

1 newton x meter

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7
Q

1 watt =

A

1 joule / second

(work / time)

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8
Q

uniform electric field

A

a field in which the value of the field strength remains the same at all points

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9
Q

resistance and conductivity relationship

A

they are inversely related!

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10
Q

resistance units

A

ohm’s

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11
Q

period vs frequency

A

period → seconds per cycle

frequency → cycles / second

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12
Q

newton units

A
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13
Q

transferase

A

enzymes that catalyse the transfer of specific functional groups (e.g. a methyl or glycosyl group) from one molecule to another (donor to acceptor)

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14
Q

nucleotide vs nucleoside

A

Nucleosides → nitrogenous base + a five-carbon carbohydrate group (usually ribose)

Nucleotides → a nucleoside with one or more phosphate groups attached

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15
Q

what is this structure called

A

heme group

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16
Q

michaelis menton plot

A

x-axis → substrate concentration

y-axis → INITIAL reaction rate (before the reverse reaction occurs)

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17
Q

why do we use smaller enzyme concentrations than substrate concentrations to measure enzyme kinetics?

A

enzyme kinetics involves seeing how the substrate concentration affects the initial reaction rate

if we have more enzyme than substrate, each trial would be the same

18
Q

what is a heme?

A

a porphyrin ring with iron in the center

19
Q

hydroxylation

A

that addition of a hydroxyl group onto a compound

20
Q

hydrolase

A

enzymes that catalyze hydrolysis (cleave bonds by adding water)

21
Q

ligase

A

enzyme that catalyzes bond formation between 2 (larger) molecules

22
Q

transferase enzyme

A

catalyze the transfer of a functional group (amine, carboxyl, carbonyl, methyl, acyl, etc.) from one molecule to another

23
Q

lyase enzyme

A

catalyzes the breaking of various chemical bonds by means other than hydrolysis and oxidation

24
Q

standard Gibb’s free energy (derived from Keq)

25
Standard free energy of a reaction
the free energy change that occurs when the ruction is carried out under standard state conditions
26
if current pH is BELOW the pKa ….
the proton is attached to the molecule still
27
if current pH is ABOVE the pKa ….
the proton has been released from the molecule into solution
28
as pH rises, molecules are being more readily _______ (protonated/deprotonated)
**deprotonated** they lose their H+ ions to solution to interact with the available base
29
isoelectric point
the pH of a solution at which the net charge of a protein becomes zero if pH \< IP; protein is positively charged if pH \> IP; protein is negatively charged
30
FORMAL CHARGE
(# valence electrons in neutral/lone atom) – (# bonds + nonbonding electrons)
31
valence electrons in nitrogen
5
32
valence electrons in oxygen
6
33
valence electrons in carbon
4
34
what is Kw?
dissociation constant or ionization constant of water **1 x 10^-14** at 298K
35
stronger acid = ______ ka
larger dissociates more readily
36
if ka \> kb, the solution is _____ (acidic/basic)
acidic
37
if kb \> ka, the solution is _____ (acidic/basic)
basic
38
aufbau principle
electrons fill lower-energy atomic orbitals before filling higher-energy ones
39
chelate
a compound containing a ligand (typically organic) bonded to a central metal atom at two or more points
40
celcius to Kelvin
K = C + 273