chapter 16 - organic synthesis Flashcards

(36 cards)

1
Q

what is the reagant for an alkane to haloalkane reaction?

A

halogen

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2
Q

what is the condition for an alkane to haloalkane reaction?

A

UV light

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3
Q

what is the mechanism for an alkane to haloalkane reaction?

A

free radical substitution

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4
Q

what type of reaction is alkane to haloalkane?

A

substitution

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5
Q

what are the reagants for an alkene to alkane reaction?

A

hydrogen, Ni catalyst

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6
Q

what is the conition for an alkene to alkane reaction?

A

150oC

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7
Q

what is the mechanism for an alkene to alkane reaction?

A

electrophilic addition

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8
Q

what type of reaction is alkene to alkane?

A

addition/hydrogenation

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9
Q

what is the reagant for an alkene to haloalkane reaction?

A

hydrogen halide

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10
Q

what is the condition for alkene to haloalkane?

A

mix at RTP

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11
Q

what is the mechanism for an alkene to haloalkane reaction?

A

electrophilic addition

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12
Q

what is the reaction for alkene to haloalkane?

A

addition

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13
Q

what is the reagant for a haloalkane to alcohol reaction?

A

NaOH

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14
Q

what is the condition for a haloalkane to alcohol reaction?

A

heat with reflux

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15
Q

what is the mechanism for a haloalkane to alcohol reaction?

A

nucleophilic substitution

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16
Q

what type of reaction is haloalkane to alcohol?

17
Q

what are the reagants for an alcohol to haloalkane reaction?

18
Q

what is the condition for alcohol to haloalkane reaction?

A

heat with reflux

19
Q

what is the mechanism for alcohol to haloalkane reaction?

A

nucleophilic substitution

20
Q

what type of reaction is alcohol to haloalkane?

21
Q

what are the reagants for alkene to alcohol reaction?

22
Q

what is the condition for alkene to alcohol reaction?

A

300oC, 60-70 atm

23
Q

what type of reaction is alkene to alcohol?

24
Q

what is the reagant for alcohol to alkene reaction?

25
what is the condition for alcohol to alkene reaction?
heat
26
what is the mechanism for alcohol to alkene reaction?
elimination
27
what type of reaction is alcohol to alkene?
dehydration/elimination
28
what are the reagants for alcohol to ketone reaction?
H+/Cr2O72-
29
what is the conditon for alcohol to ketone reaction?
heat under reflux
30
what type of reaction is alcohol to ketone?
oxidation
31
what are the reagants for alcohol to carboxylic acid reaction?
H+/Cr2O72-
32
what is the condition for alcohol to carboxylic acid reaction?
heat with reflux
33
what type of reaction is alcohol to carboxylic acid?
complete oxidation
34
what are the reagants for alcohol to aldehyde reaction?
H+/Cr2O72-
35
what is the condition for alcohol to aldehyde reaction?
distillation
36
what type of reaction is alcohol to aldehyde?
partial oxidation