Chapter 17 Flashcards
(36 cards)
Explain Lipids and their functions.
- Lipids are hydrocarbon like molecules
- They are insoluble in water
Functions:
- To store energy
- Components of membranes
- Chemical Messengers
What are the types of Lipids?
- Fatty Acids
- Glycerides
- Non Glyceride lipids
- Complex Lipids
Explain how plants store energy.
Plants store energy as starch
- Starch is a carbohydrate polymer
Explain how animals store energy.
Animals store energy as fats
- Stored in adipose tissue
- Lipids reserves can maintain the human body for 30 days with water.
Explain Membrane Components.
Lipid membrane separates cellular components
- The hydrocarbon end of the lipid is hydrophobic.
- The opposite end is hydrophilic.
Explain Chemical Messengers.
Primary Messengers:
- Delivers chemical signals from one part of the body to another.
Secondary Messengers:
- Mediate the hormonal responces.
Explain Triacylglycerols (Triglycerides)
Triglycerides are the major form of energy storage for animals.
- In the body fatty acid are stored as Triglycerides.
How is a Triglycerides made?
Esters of glycerol and 3 long fatty acid chains.
Explain the Structure of Lipids.
- Fatty acid lipids are all unbranched carboxylic acids
- The carboxylic acid chains contain an even number of carbon atoms
- Some acids contain double bonds, in those that have double bonds the cis isomer predominates.
Explain the Properties of Lipids.
- They are insoluble in water
- Fats from animals are solid and are saturated.
- Oils from plants are liquid and unsaturated.
Explain Animal Fats.
Straight chain fatty acids allow the molecules to be closely packed together increasing the attractive forces between molecules.
Explain Plant Fats.
The cis double bond interrupt the close packing of the fatty acid chain and disrupts the attraction between acid molecules.
Can humans synthesize fatty acids?
Humans are capable of synthesizing some fatty acids from carbohydrates or other fatty acids, but we cannot synthesize sufficient amounts of polyunsaturated fatty acids.
- Because of this, polyunsaturated fatty acids must be obtained from diet as they are known as essential.
What is Saponification?
The reaction of a fat with a strong base in the presence of heat to create soap.
- It splits triglycerides into glycerol and the salts of fatty acids.
Explain the structure and solubility of carboxylic acid salts.
The solubility of carboxylic acid salts having 12-18 carbons is governed by two different structural units.
- Long nonpolar hydrocarbon chain: Hydrophobic
- Polar carboxylate group: Hydrophilic
Explain the structure of Soaps.
In aqueous solutions molecules orient themselves into micelles.
- The hydrocarbon tail is pointed inward and the carboxylate group is pointed outward toward the surrounding water.
Explain Synthetic Detergents.
Most cleaning substances are detergents, it cleans like soap but dosent form soap scum
What are phospholipids?
Phospholipids are a family of lipids similar in structure to triglycerides. They include glycerophospholipids and sphingomyelin.
What are Glycerophospholipids made of?
- Two fatty acids that form esters bonds with the first and second hydroxyl groups of glycerol.
- A hydroxyl group that forms an ester with phosphonic acid, which form another phosphodiester bond with an animo acid.
What is Lecithin and Cephalin?
Two types of glycerophospholipids that are abundant in brain and nerve tissue and found in yolk, whear, and yeast.
Explain the Structure and Polarity of Glycerophospholipids.
- They contain polar and nonpolar regions that allow them to interact with polar and nonpolar substances.
- They have a polar head containing ionized amino alcohol and phosphate portions, which is strongly attracted to water.
- They have a nonpolar hydrocarbon tail portion soluble only in nonpolar substances such as lipids.
Explain Sphingomyelin.
It contains:
- Sphingosine instead of glycerol
- A fatty acid, phosphate, and amino acid
Explain Cell Membranes.
- They are semipermeable so that nutrients can enter the cell and waste products can leave.
- They seperate cellular contents from the external environments.
- Consist of a lipid bilayer made of two rows of phospholipids.
- Hava an inner portion made of the nonpolar tails and phospholipids, with the polar heads at the outer and inner surfaces.
Explain Fluid Mosaic Membrane.
Called a Mosaic because of imbedded proteins and other substances that float in the lipid bilayer.