Entropy Flashcards

1
Q

What is entropy?

A

A measurement of disorder

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2
Q

The higher the disorder….

A

The higher the entropy.

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3
Q

What is entropy symbol?

A

S

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4
Q

How does raising the temperature of a substance affect its entropy?

A

Raising the temperature of a substance increases its disorder which increases its entropy

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5
Q

When a substance changes state what happens to entropy?

A

If it changes from solid to liquid entropy increases.
If it changes from liquid to gas its entropy increases even more.

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6
Q

If two substance are in the same state can you predict their entropy?

A

No only if they are in different states.

Eg. One lis liquid and one is solid

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7
Q

How does dissolving a solid affect its entropy?

A

Dissolving a solid in water increases its entropy as it becomes aqueous.

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8
Q

How does increasing the number of particles in the reaction affect entropy?

A

more products than reactants= higher entropy
one reactant breaking down into two or more products makes a higher entropy.

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9
Q

How does you find entropy change?

A

entropy change= heat/temperature

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10
Q

what is the entropy of substances at zero kelvin?

A

zero

this is because the particles aren’t moving so therefore no zero disorder.

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11
Q

define the standard molar entropy

A

the entropy of one mole of a substance at 298K

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12
Q

If a reaction is exothermic what happens?

A

it increases the entropy of the surrounding and therefore entropy change will be positive.

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13
Q

If a reaction is endothermic, what happens?

A

it decreases the entropy of the surrounding so therefore entropy change is negative.

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14
Q

For any reaction to occur, what does the entropy change have to be?

A

entropy change has to be positive.

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15
Q

when are reactions feasible

A

if the entropy of the universe increases

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16
Q

state the second law of thermodynamics is.

A

for any process to happen, it must increase the entropy of the universe.

17
Q

how do you calculate gibbs free energy?

A

gibbs free energy change= enthalpy change - T Entropy change

18
Q
A