Acids and base Flashcards

(61 cards)

1
Q

HCl

A

Acid

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2
Q

H2SO4

A

Acid

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3
Q

HNO3

A

Acid

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4
Q

CH3COOH

A

acid

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5
Q

KOH

A

Base

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6
Q

NaOH

A

Base

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7
Q

Ba(OH)2

A

Base

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8
Q

What is the general equation for a neutralisation reaction?

A

Acid+ base —>salt + water

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9
Q

When an acid + metal react what do they form?

A

Salt+ hydrogen

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10
Q

When an acid and metal oxide react what do they form?

A

Salt + water

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11
Q

When an acid and metal carbonate react, what do they form?

A

Salt + carbon dioxide + water

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12
Q

What is the Arrhenius model?

A

Acids and bases are defined based on how they dissolve in water.

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13
Q

Arrhenius acids?

A

Dissociate to give
H+ ions

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14
Q

Arrhenius bases?

A

Dissociate to give
OH- ions

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15
Q

What is the brondsted Lowry model?

A

Acids and bases are defined based on how they react

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16
Q

Bronsted Lowry acid?

A

Proton donator

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17
Q

Bronsted Lowry base?

A

Proton acceptor

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18
Q

Define acidity?

A

Concentration of H+ ions

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19
Q

How do you find pH?

A

pH= -log10[H+]

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20
Q

How do you find concentration of H+ ions form pH?

A

[H+]=10^-pH

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21
Q

What does water dissociate into?

A

H2O=H+ + OH-

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22
Q

What is the equilibrium constant for water dissociation?

A

Kw
(Ionic product of water)

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23
Q

What unit does Kw have?

A

Mol2 dm-6

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24
Q

How does temperature affect pH?

A

The ionisation of water is endothermic. So increasing the temperature shifts the equilibrium to the right. This increases the concentration of H+ ions and so decreases the pH.

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25
Explain how Kw increases as temperature increases?
The ionisation of water is endothermic p so increasing temperature shifts the equilibrium to the right. This increases the concentration of H+ and OH- ions, which increases Kw.
26
How does the low solubility of some group 2 hydroxide affect pH?
Some group 2 has low hydroxides have low solubility as a result salts don’t fully dissolve and leading to a pH value which isn’t always as high as expected.
27
Why is water always neutral?
As the concretatuon of OH- and H+ ions are equal
28
When weak acids dissociate what do they form?
Dynamic equilibrium
29
What is the equilibrium constant for this reaction?
Ka (Acid dissociation constant
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What is the unit for Ka?
Mol dm-3
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The larger the Ka for an acid….
The stronger the acid
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To make it easier to compare Ka values what is used
pKa value is used
33
How do you find pKa?
pKa =-log(Ka)
34
How do you find Ka from pKa?
10-pKa
35
The smaller the pKa value..
The stronger the acid is
36
What is an monoprotic acid?
Produces 1 proton.
37
Examples of monoprotic acids
HCl HNO3 CH3COOH
38
What is a diprotic acid?
Produces 2 protons
39
Examples of diprotic acids
H2SO4
40
What is a triprotic acid?
Produces 3 protons
41
Which proton dissociates strongly?
1st proton
42
Which proton dissociates weakly ?
2nd and 3rd
43
How do you find pH after a neutralisation reactions?
Find which reactant is in excess. Calculate the amount of the excess reactant once the reaction is complete. Use your answer to step 2 alongside the volume to find concentration of [H+]or [OH-]. Find pH.
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What is a buffer solution?
A buffer solution resists changes in pH when small amounts of acid or base are added.
50
What do buffer solutions contain?
Must containHA and A- The concentration of HA and A- must be high.
51
How to make a buffer solution?
Mixing a weak acid with the salt of its conjugate base. Or partially neutralising a weak acid with a strong base.
52
Equation of a buffer solution.
HA= H+ + A-
53
What happens when small amounts of acid or base are added to the buffer?
The equilibrium position shifts to maintain the concentration of H+.
53
Adding acid to a buffer solution
Adding HCl increases the concentration of H+ ions which makes the equilibrium shift to the left. This decreases the concentration of H+
54
Adding a bases to a buffer solution.
Add NaOH. OH- + H+—>H2O this decreases the concentration of H+ ions so the equilibrium shifts to the right. D increase the concentration of H+