Gas Laws - Quiz 4 Flashcards

(40 cards)

1
Q

What are the 4 quantities that describe the state of a gas?

A

Pressure

Temperature

Volume

Number of Moles

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2
Q

What is Standard Temperature & Pressure?

A

273.15 Kelvin

1 Atm

One Mole of gas @ STP has volume of 22.7 L

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3
Q

Boyle’s Law

A

P1V1 = P2V2

Volume is Inversely Related to Pressure

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4
Q

Charles’s Law

A

V1/T1 = V2/T2

Volume is Directly Proportional to Temperature

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5
Q

Avagadro’s Law

A

V1/n1 = V2/n2

Volume of Gas is Directly Proportional to Number of Gas Molecules

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6
Q

What is Avaogadro’s Number?

A

6.022 x 1023

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7
Q

Gay-Lussacs Law

A

P1/T1 - P2/T2

Pressure is Directly Proportional to Temperature

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8
Q

Ideal Gas Law

A

PV = nRT

Ideal Gases Dont Exist

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9
Q

What is the Universal Gas Constant (R)?

A

R = 0.08205 L atm/mol-1 K-1

or

R = 8.314 J/mol/K

Describes relationship b/t Tmperature & Kinetic Energy

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10
Q

What does Gas Density Depend on?

A

Temperature & Pressure

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11
Q

Dalton’s Law

A

Total Pressure of a mix of gases is equal to Sum of the Partial Pressures

Ptotal = P1 + P2 + P3….

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12
Q

How to calculate Mole Fraction?

A

Divide # moles of a specific gas by the total number of moles in the mixture

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13
Q

What does Relatively Humidity measure?

A

Saturation of Water in Air

RH = Mass of Water in air / Mass of water that will fit in air

Warmer air holds more water

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14
Q

As Temperature Decreases, Relative Humidity will _________

A

Temperature Decrease = Relative Humidity Increase

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15
Q

What is the Dew Point?

A

The temperature at which Relateive Humidity = 100% and where water saturates the air.

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16
Q

What is the Kinetic Theory of Gases?

A

Gas molecules are small and are in constant, random motion frequently bumping into each other and the walls.

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17
Q

What does the average Kinetic Energy of gas molecules depend on?

A

Temperature, Not Gas Identity

Higher Temperature = Higher Motion

18
Q

What is the definition of Gas Pressure?

A

Force of gas molecules / Volume

19
Q

How is Gas Density calculated?

A

Mass of gas molecule / Volume occupied by gas

20
Q

What is Internal Energy?

A

Sum of Kinetic Energy & Potential Energy

21
Q

What is the difference between The Boltzmann Constant & Ideal Gas Constant?

A

Boltzmann Constant deals with individual molecules

Ideal Gas Constant deals with Moles of Molecules

22
Q

What is Effusion?

A

Movement of gas through a small opening

23
Q

What is Diffusion?

A

When something moves from area of higher concentration to area of lower concentration

24
Q

Graham’s Law

A

Rate of Effusion is Inversely Proportional to square root of molecular mass

and depends on Speed of Molecules

(Diffusion Rate inversely propotional to Size of Molecule)

25
Fick's Law
Rate of Gas Diffusion depends on * Membrane's Chemical Properties * Membrane Surface Area * Membrane Thickness * Partial Pressure Gradient
26
How is Diffusion Rate related to Membrane Thickness & Molecular Weight?
Diffusion Rate is **Inversely Proportional** to membrane thickness & molecular weight
27
Diffusion rate is __________ proportional to Partial Pressure Gradient, Membrane Area, and Solubility of Gas
Diffusion rate is **Directly** proportional to Partial Pressure Gradient, Membrane Area, and Solubility of Gas
28
What is Diffusion-Limited Gas Exchange
Gas from alveoli to tissues is limited by alevolar membrane
29
What is Perfusion-Limited Gas Exchange?
Gas from alveoli to tissues is limited by rate of blood flow through pulmonary capillaries.
30
What is Diffusion Hypoxia
When anesthetic gases diffuse out of the blood and back into the lungs lowering the O2 concentration.
31
What gas effects can be explained by Fick's Law?
Concentration Effect Second Gas Effect Diffusion Hypoxia Why N2O increases volume/presure in gas spaces
32
What is the process by which the fetus receives O2 & Drugs?
Simple Diffusion
33
Henry's Law
The amount of dissolved gas in a liquid is proportional to its partial pressure above the liquid
34
The colder the liquid, the ______ gas will dissolve in the liquid
The colder the liquid, the **more** gas will dissolve in the liquid
35
Ostwald's Solubility Coefficient
The Higher the Coefficient, the more readily the gas dissolve in the liquid
36
Meyer Overton
The more lipid soluble the gas, the greater the potency
37
Vander Waals Equation
Since there are no ideal gases, this equation takes into account **finite volumes & attraction of gas molecules.**
38
What is the Joule-Thompson Effect?
Cooling Effect when fluid expands from high pressure to low pressure
39
What is Adiabatic Compression
Process of compression w/o adding or subtracting heat Heat is generated, which increases pressure, d/t decrease in volume
40
How does the Soda Lime chemically work?
CO2 + H2O ------------\> H2CO3 (Carbonic Acid) Heat + H2CO3 + 2NaOH ------------\> Na2CO3 + 2H2O Na2CO3 + Ca(OH)2 (Calcium Hydroxide) ------------\> NaOH + CaCO3 (Calcium Carbonate)