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INORG CHEM LEC > GROUP VIII & H > Flashcards

GROUP VIII & H Flashcards

(93 cards)

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1
Q

NEON GROUP

A

GROUP VIIIA

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2
Q
  • the NOBLE GASES
  • inert gas/elements
  • chemically inert/stable/unreactive
  • monoatomic gases
  • all except Rn occur in the atmosphere
A

NEON GROUP / GROUP VIIIA

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3
Q

what element in the neon group does not occur in the atmosphere

A

RADON

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4
Q

produced during natural decay of radium

A

RADON

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5
Q
  • SUN
  • mixed with ANESTHETIC GASES
A

HELIUM

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6
Q

ARTIFICIAL AIR

A

20% O2 + 80% He

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7
Q
  • NEW
  • used in SIGNS due to BRIGHT REDDISH ORANGE light
A

NEON

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8
Q

as DIVING gas for deep levels

A

ARTIFICIAL AIR

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9
Q
  • LAZY
  • used to DISPLACE OXYGEN and moisture-containing air in packaging material to EXTEND SHELF-LIVES of the contents
A

ARGON

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10
Q
  • HIDDEN
  • used in some PHOTOGRAPHIC FLASHES for HIGH SPEED PHOTOGRAPHY
A

KRYPTON

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11
Q
  • STRANGER
  • used as general anesthetic (more costly)
A

XENON

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12
Q
  • anticancer
A

RADON

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13
Q
  • used extensively in the form of alloys for utensils, COINS, surgical instruments
  • German silver: Ni + Cu+ Zn
A

NICKEL

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14
Q

German silver

A

Ni + Cu + Zn

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15
Q
  • used as ADSORBENT FOR H2 in gas analysis
  • alloys with GOLD (white gold) -> jewelry, dental practice, coating
A

PALLADIUM

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16
Q

PLATINUM came from the spanish word

A

PLATINA

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17
Q

PLATINA means

A

SILVER

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18
Q
  • RESISTANT TO CORROSION
  • dissolves in aqua regia
  • used in the preparations of crucibles, dishes, and platinum wires
  • MORE EXPENSIVE jewelry than gold
A

PLATINUM

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19
Q
  • FINELY DIVIDED FORM of platinum
  • catalyst in fuel cells
A

PLATINUM BLACK

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20
Q
  • ANTICANCER AGENT with platinum
  • binds to DNA and causes cross-linking, which triggers the PROGRAMMED CELL DEATH (APOPTOSIS)
  • discovered by Rosenberg in 1965 serendipitously (by accident)
A

CISPLATIN

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21
Q

CISPLATIN was discovered by

A

ROSENBERG

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22
Q

SIDE EFFECTS OF CISPLATIN

A

NAUSEA AND VOMITING
NEPHROTOXICITY - kidney poisoning
DOSE-LIMITING

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23
Q

side effects of cisplatin that is the LOSS OF HIGH-FREQUENCY HEARING

A

OTOTOXICITY

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24
Q

side effects of cisplatin that is the DAMAGE TO NERVES OF THE PERIPHERAL NERVOUS SYSTEM

A

PERIPHERAL NEUROPATHY

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25
side effects of cisplatin that is the BONE MARROW SUPPRESSION; REDUCES THE PATIENTS' WBC COUNT and makes them susceptible to infections
MYELOSUPPRESSION
26
- 2ND GENERATION platinum based anticancer drug - LESS REACTIVE and has LESS NEPHROTOXIC AND OTOTOXIC - MORE MYELOSUPPRESSIVE
CARBOPLATIN
27
- 3RD GENERATION platinum based anticancer drug - MOST EFFECTIVE in combination with: 5-fluorouracil and leucovorin in the treatment of metastatic carcinomas of the colon/rectum
OXALIPLATIN
28
- ORALLY ACTIVE, convinient to the patient - milder toxicity - no cross-resistance -NOT APPROVED BY FDA
SATRAPLATIN
29
IRON latin name
FERRUM
30
FERRUM means
STRONG
31
- WIDELY USED METAL - low production cost - high strength - steel : Fe + C - Chalybeate water
IRON
32
IRON-CONTAINING WATER
CHALYBEATE WATER
33
STEEL
Fe + C
34
Fe3O4
MAGNETITE
35
Fe2O3
HEMATITE
36
FeS2
PYRITE
37
also known as FOOL'S GOLD
PYRITE FeS2
38
- PURE IRON is RESISTANT to OXIDATION - Rusting (ferric oxide) is probably due to IMPURITIES
ELEMENTAL IRON
39
what causes rusting of iron
IMPURITIES
40
- divalent, reduced form - colorless in anhydrous form - GREEN IN HYDRATED FORM - reducing agents
FERROUS SALTS Fe+2
41
- trivalent, oxidized form - YELLOWISH TO BROWN IN ANHYDROUS FORM - oxidizing agents - give RED PPT with tannins
FERRIC SALTS Fe+3
42
- astringent - styptic: stops bleeding when applied to wound - hematinic: stimulate RBC production
IRON
43
common side effect of IRON preparations
BLACK STOOL
44
- ESSENTIAL TRACE ELEMENT
IRON
45
- OXYGEN-TRANSPORT metalloprotein in RBC
HAEMOGLOBIN
46
- facilitates O2 use and storage in MUSCLES
MYOGLOBIN
47
- TRANSPORT ELECTRONS
CYTOCHROMES
48
- lethargy and weakness - iron supplementation
IRON-DEFICIENCY ANEMIA
49
- 8x LESS EFFECTIVE than ferrous sulfate
FERRIC AMMONIUM CITRATE
50
- treatment of anemia requiring IRON AND ARSENIC
FERRIC CACODYLATE
51
- atringent, styptic, hematinic
FERRIC CHLORIDE
52
- RED and YELLOW form - colorant, SIMULATE SKIN COLOR (e.g. in calamine)
FERRIC OXIDE
53
- FERROUS CARBONATE MASS - FERROUS CARBONATE PILLS
FERROUS CARBONATE
54
- VALLET'S MASS - hematinic
FERROUS CARBONATE MASS
55
- CHALYBEATE PILLS, FERRUGINOUS PILLS - hematinic
FERROUS CARBONATE PILLS
56
- MOST COMMON, LEAST EXPENSIVE - common side effect: GASTRIC DISCOMFORT
FERROUS SULFATE
57
common side effect of FERROUS SULFATE
GASTRIC DISCOMFORT
58
GREEN VITRIOL (ferrous sulfate in powder form)
FeSO4 H2O
59
- LESS GASTRIC IRRITATION than ferrous sulfate
FERROUS GLUCONATE
60
- MOST EXPENSIVE (ferrous)
FERROUS FUMARATE
61
- DIALYZED IRON - antidote for ARSENIC POISONING
FERRIC HYDROXIDE
62
- MOHR'S SALT - used as indicator in Ag titrations
FERROUS AMMONIUM SULFATE
63
- RED PRUSSIATE OF POTASH
POTASSIUM FERRICYANIDE
64
- YELLOW PRUSSIATE OF POTASH
POTASSIUM FERROCYANIDE
65
- TURNBULL'S BLUE
FERROUS FERRICYANIDE
66
- PRUSSIAN BLUE - antidote for THALLIUM POISONING
FERRIC FERROCYNIDE
67
COBALT came from the german word
KOBOLD
68
KOBOLD means
GOBLINE OR GNOME
68
- PINKISH WHITE METAL - stimulate HEMATOPOIESIS (formation of blood cellular components - parenteral: BP lowering, capillary damage - oral: vomiting and diarrhea
COBALT
69
- RINMAN'S GREEN - paint pigment
COBALTOUS OXIDE
70
- astringent antiseptic powder
COBALTO-COBALTIC OXIDE
71
- basis of INVISIBLE or SYMPATHETIC INKS - TIRNS BLUE WHEN WARMED
COBALTOUS CHLORIDE
72
- alloy of Rh + Pt -> HARDER, MORE DURABLE than Pt alone
RHODIUM
73
- HEAVIEST, DENSEST ELEMENT - Osmium tetroxide
OSMIUM
74
- OSMIC ACID - used for HARDENING AND COLORING (black) HISTOLOGICAL SPECIMENS
OSMIUM TETROXIDE
75
- INFLAMMABLE AIR - an ESSENTIAL CONSTITUENT OF ALL ACIDS - "water-producing" (A. Lavoisier)
HYDROGEN
76
HYDROGEN means
WATER-PRODUCING
77
Who coined the term hydrogen
A. Lavoisier
78
- colorless, tasteless, odorless gas - burns with a PALE BLUE NON LUMINOUS FLAME - a reducing agent with Pd, Ni or Pt as catalyst
HYDROGEN GAS
79
it is obtained by: - electrolysis of WATER CONTAINING CAUSTIC SODA - FRACTIONATION of water gas - passing steam over incandescent iron - reaction of some metals (Na, K) with water
HYDROGEN GAS H2
80
- In haber process for NITROGEN FIXATION - INFLATING BALLOONS - production of high temperature w/ oxygen - hydrogenation of edible oils
HYDROGEN GAS H2
81
(isotope of hydrogen) - MOST ABUNDANT, naturally occuring
PROTIUM (HYDROGEN 1)
82
(isotope of hydrogen) - naturally occuring
DEUTERIUM (HYDROGEN 2)
83
(isotope of hydrogen) - a radioactive tracer
TRITIUM (HYDROGEN 3)
84
- HEAVY WATER - used as tracer compound
DEUTERIUM OXIDE
85
- NATURAL SPRING or WELL WATERS
MINERAL WATERS
86
WATER w/ Na and Mg sulfates + NaHCO3
ALKALINE WATER
87
- WATER charged with CO2 under pressure - used in softdrinks
CARBONATED WATER
88
WATER w/ iron characterized by FERRUGINOUS TASTE
CHALYBEATE WATER
89
water w/ LITHIUM CARBONATES OR CHLORIDES
LITHIA WATER
90
- PURGATIVE WATER - water w/ Na and Mg sulfates + NaCl
SALINE WATER
91
water w/ HYDROGEN SULFIDE (hot springs)
SULFUR WATER
92
water w/ ALKALI SILICATES
SILICEOUS WATER

INORG CHEM LEC (8 decks)

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