MIDTERM 11 - Alkaloids Flashcards

1
Q

Derived from amino acid and share a heterocyclic ring with nitrogen (Types of alkaloids)

A

True alkaloids

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2
Q

Compounds which the N atom is derived from amino acids and not part of heterocyclic ring (Types of alkaloids)

A

Proto/amino alkaloids

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3
Q

Cocaine, quinine, and morphine are examples of __________

A

True alkaloids

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4
Q

Hordenine, mescaline, and yohimbine are examples of ___________

A

Proto/amino alkaloids

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5
Q

The basic carbon skeletons of which are not derived from amino acid (Types of alkaloids)

A

Pseudo alkaloids

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6
Q

Are non alkaloids that give a false positive reaction with alkaloidal reagents (Types of alkaloids)

A

False alkaloids

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7
Q

Coniine, capsaicin, ephedrine, caffeine, and theobromine are examples of __________

A

Pseudo alkaloids

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8
Q

Most alkaloids are __________, only a few alkaloids are amorphous (like emetine)

A

Crystalline solid

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9
Q

Majority of alkaloids are __________

A

Colorless

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10
Q

Colchicine and berberine are color __________

A

Yellow

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11
Q

Canadine is color __________

A

Orange

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12
Q

Salts of sanguinarine are color _________

A

Copper red

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13
Q

Alkaloidal bases and salts are soluble in __________

A

Alcohol

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14
Q

Most of the alkaloids ends in __________

A

“-ien”

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15
Q

All alkaloids are solids, except __________, __________, __________, and __________ (CANS)

A

Coniine, Arecoline, Nicotine, Sparteine

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16
Q

Derived from Coniium maculatum (poison hemlock)

A

Coniine

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17
Q

Cocaine (Stimulant, hallucinogen, or depressant)

18
Q

Ephedrine (Stimulant, hallucinogen, or depressant)

19
Q

Caffeine (Stimulant, hallucinogen, or depressant)

20
Q

Tropane alkaloids (Stimulant, hallucinogen, or depressant)

A

Hallucinogen

21
Q

Mescaline (Stimulant, hallucinogen, or depressant)

A

Hallucinogen

22
Q

Ergot alkaloids (Stimulant, hallucinogen, or depressant)

A

Hallucinogen

23
Q

Morphine (Stimulant, hallucinogen, or depressant)

A

Depressant

24
Q

Codeine (Stimulant, hallucinogen, or depressant)

A

Depressant

25
Heroin (Stimulant, hallucinogen, or depressant)
Depressant
26
Nicotinic precursor
Nicotine
27
Purine precursor
Caffeine
28
Some alkaloids are synthesized from __________ along mevalonic acid pathway
Terpenes
29
Atropine is an example of __________
True alkaloid
30
Ephedrine is an example of __________
Protoalkaloid
31
Caffeine is an example of __________
Pseudo alkaloid
32
Reddish-brown/Brown ppt (Chemical test for alkaloids)
Wagner's test
33
Wagner's test (Positive result)
Reddish-brown/Brown ppt
34
White/Cream color ppt with true alkaloids (Chemical test for alkaloids)
Mayer's test
35
Mayer's test (Positive result)
White/Cream color ppt with true alkaloids
36
Yellow ppt with true alkaloids (Chemical test for alkaloids)
Hagger's test
37
Hagger's test (Positive result)
Yellow ppt with true alkaloids
38
Reddish brown ppt/Orange yellow ppt/ Orange ppt (Chemical test for alkaloids)
Dragendorff's test
39
Dragendorff's test (Positive result)
Reddish brown ppt/Orange yellow ppt/ Orange ppt
40
Are alkaloids that arise by inclusion of a basic nitrogen at some point in the steroid molecule; C27 compounds having cyclopentanophenanthrene moiety
Steroidal alkaloids