13.2, 15.1, 15.2, 16.1 Flashcards

(73 cards)

1
Q

evaporation

A

vaporization that occurs at the surface of a liquid that is not boiling

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2
Q

boiling

A

vaporization throughout the liquid when vapor pressure is equal to the outside pressure

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3
Q

boiling point

A

the temperature at which the vapor pressure of a liquid is just equal to the external pressure on the liquid

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4
Q

normal boiling point

A

the boiling point of a liquid at a pressure of 101.3 kPa or 1atm

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5
Q

solvation

A

a process that occurs when an ionic solute dissolves

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6
Q

what happens when things dissolve in a solution

A

solvent molecules surround the positive and negative ions

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7
Q

vapor pressure

A

a measure of the force exerted by a gas above a liquid in a sealed container
a dynamic equilibrium exists between the vapor and the liquid

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8
Q

surface tension

A

an inward force that tends to minimize the surface area of a liquid
it causes the surface to behave as if it were a thin skin

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9
Q

solution

A

a homogeneous mixture, consists of solutes dissolved in a solvent

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10
Q

solvent

A

the dissolving medium in a solution

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11
Q

solute

A

dissolved particles in a solution

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12
Q

soluble

A

tendency to dissolve in a specific amount of solvent at a specified temperature and presssure

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13
Q

insoluble

A

tendency not to dissolve

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14
Q

diple

A

a molecule that has two poles, or regions, with opposite charges

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15
Q

miscible

A

describes liquids that dissolve in one another in all proportions

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16
Q

immiscible

A

describes liquids that are insoluble in one another

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17
Q

example of immiscible

A

oil and water

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18
Q

saturated

A

maximum amount of solution

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19
Q

unsaturated

A

less than maximum amount of solution

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20
Q

supersaturated

A

more solute than it can hold at a given temperature

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21
Q

two biggest differences between a liquid and a gas

A

the particles are farther apart in a liquid

intermolecular forces important in a liquid, negligible in a gas

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22
Q

what happens to a liquid as it evaporates

A

average kinetic energy goes up, intermolecular forces are broken from the surface and some particles turn into a gas

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23
Q

what happens to the temperature of a liquid as it evaporates

A

it goes down

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24
Q

what affects the rate of evaporation? How and why?

A

heating speeds it up because the kinetic energy of the particles increases

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25
in a closed container, what is going on between the liquid and the vapor?
vapor pressure increases until it reaches dynamic equilibrium rate of evaporation = rate of condensation the liquid partices at the surface vaporize and produce increased vapor pressure, so then they later condense and return to liquid state
26
how does an increase in the temperature of a contained liquid affect the kinetic energy? Vapor pressure?
it increases them both
27
can a boiling liquid ever be increased above the boiling point by adding more energy
no
28
how can water be made to boil above the normal boiling point
higher external pressure
29
what are the six phase changes and what phases do they convert between
``` sublimation - solid to gas deposition - gas to solid evaporation - liquid to gas condensation - gas to liquid freezing - liquid to solid melting - solid to liquid ```
30
what are the conditions of a polar bond
two different atoms | asymmetrical
31
what are the conditions for a non-polar molecule
2 same atoms | symmetry
32
how many bonding pairs of electrons are there in water
2
33
how many non-bonding pairs are there
2
34
what is the shape of water
bent
35
what is electronegativity
the ability of an atom to attract electrons when the atom is in a compound
36
which part of the periodic table are elements with the greatest electronegativities found?
top right
37
which elements do not have electronegativity values and why
noble gases full don't bond
38
which element in water has the highest electronegativity
oxygen
39
which element in water has the lowest electronegativity
hydrogen
40
Which element in water pulls the electrons closer to it
oxygen
41
what is the charge on oxygen in water
slightly negative
42
what is the charge of hydrogen in water
slightly positive
43
Is water a polar molecule
yes
44
what is hydrogen bonding
positive attracts to negative of another attractive forces in which a hydrogen covalently bonded to a very electronegative atom is also weakly bonded to an unshared electron pair of another electronegative atom
45
what are two consequences of hydrogen bonding in water
high surface tension | low vapor pressure
46
what does a surfactant do
interferes with hydrogen bonding and reduces surface tension
47
example of surfactant
detergent
48
bonds between water molecules are
hydrogen bonds
49
bonds between the H and O within a water molecule are
polar covalent bonds
50
Why does water have such a high boiling point compared to other compounds
hydrogen bonding causes high surface tension, particles can't break up as easily
51
why does it take so much energy to melt ice
hydrogen bonding
52
how can the boiling point be adjusted or changed
increased pressure will increase boiling point | increased altitude will lower boiling point
53
why is ice less dense than water
hydrogen bonds hold water in open framework
54
what is a homogeneous solution
solution that is uniform in composition
55
can the solute be filtered out from the solvent in a homogeneous solution
no
56
what types of substances can be dissolved in each other
like polar in polar nonpolar in nonpolar
57
what solutes form an electrolyte when dissolved in water
ionic compounds
58
under what other conditions do ionic compounds conduct electricity
when they are molten and soluble
59
what solutes are most likely to dissolve in water
ionic and polar
60
what solutes form non-electrolytes when dissolved in water
molecular compounds
61
what type of solution can conduct electricity
electrolytes
62
what types of elements for electrolytes
ionic
63
are all molecular compounds non-electrolytes
no
64
what molecular compounds are electrolytes
acids | NH3
65
What is the difference between weak and strong electrolytes
strong electrolyte - strong electric current, dissociate into ions completely weak electrolyte - weak electric current, few ions dissociate
66
vaporization
the conversion of a liquid to a gas or vapor
67
Why might an ionic compound not dissolve in water
not soluble - attractions are stronger
68
how could you tell whether a compound would dissolve in water or not
solubility table
69
what affects the rate of dissolving
stirring temperature surface area
70
what is the expression for solubility
the number of grams of solute per 100g of solvent at a certain temperature
71
what affects the solubility of a solute and how?
temperature, pressure, nature of solvent (polar, nonpolar) | temp goes up, solubility goes up
72
what affects the solubility of a gas
temperature and pressure
73
how could you tell whether a solution was supersaturated
drop solute in and if it crystallizes is supersaturated