8.3.2 Transition Metals and Nonmetals Flashcards
Transition Metals and Nonmetals
- Understanding the periodic table is imperative to understanding the reactivity of elements.
- Transition Metals are characterized by partially filled d orbitals.
- Rare earth elements are electron rich and they tend to lose electrons in reactions
note
- Elements in the same group have similar reactivity.
- Each family reacts characteristically with hydrogen (e.g. HF, H 2 O, NH 3 , CH 4 ).
- When transition metals form cations, the s electrons are lost before the d electrons.
- Transition metals are generally harder and have higher
melting points than the alkali metals and the alkaline earth metals. - Like the transition metals, the rare earths are very electron rich and they tend to lose electrons in reactions.
- The s orbital fills before the f orbital; but when rare earths form cations, the s electrons are again the first to be lost.
- The noble gases are relatively unreactive, but become more reactive as you move down the group on the periodic table.
Which of the following is the correct electron configuration for titanium(II) cation?
[Ar] 3d2
The rare earth or inner transition metals often have two s electrons and one d electron as well as a variable number of electrons in the f energy sublevel. As a result of this curious behavior, the rare earth elements often form cations with what charge?
3+
Which noble gas forms a compound with what other element?
Xenon with fluorine
Using the noble gas configuration, what is the electron configuration for vanadium?
[Ar] 3d34s2
Which of the following is the best statement describing a transition metal.
- Any element with a partially filled d orbital.
- Any element in the middle block of the periodic table
- Any element whose 3d orbitals have a higher energy than the 4s orbitals
What is the electron configuration of titanium?
1s22s22p63s23p64s23d2
How do the transition metals compare to the alkali and alkaline earth metals?
Transition metals are harder and denser.
In most of the transition metals, the d orbitals fill up after the s orbitals of the next higher principal quantum number. Why does this occur?
Because the s orbitals have a lower energy
Transition metals form a variety of different charged cations. What is the most common charge on the cation formed by the transition metals?
2+
Metals are generally involved in the formation of which of the following?
Cations