8.3.2 Transition Metals and Nonmetals Flashcards

1
Q

Transition Metals and Nonmetals

A
  • Understanding the periodic table is imperative to understanding the reactivity of elements.
  • Transition Metals are characterized by partially filled d orbitals.
  • Rare earth elements are electron rich and they tend to lose electrons in reactions
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2
Q

note

A
  • Elements in the same group have similar reactivity.
  • Each family reacts characteristically with hydrogen (e.g. HF, H 2 O, NH 3 , CH 4 ).
  • When transition metals form cations, the s electrons are lost before the d electrons.
  • Transition metals are generally harder and have higher
    melting points than the alkali metals and the alkaline earth metals.
  • Like the transition metals, the rare earths are very electron rich and they tend to lose electrons in reactions.
  • The s orbital fills before the f orbital; but when rare earths form cations, the s electrons are again the first to be lost.
  • The noble gases are relatively unreactive, but become more reactive as you move down the group on the periodic table.
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3
Q

Which of the following is the correct electron configuration for titanium(II) cation?

A

[Ar] 3d2

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4
Q

The rare earth or inner transition metals often have two s electrons and one d electron as well as a variable number of electrons in the f energy sublevel. As a result of this curious behavior, the rare earth elements often form cations with what charge?

A

3+

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5
Q

Which noble gas forms a compound with what other element?

A

Xenon with fluorine

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6
Q

Using the noble gas configuration, what is the electron configuration for vanadium?

A

[Ar] 3d34s2

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7
Q

Which of the following is the best statement describing a transition metal.

A
  • Any element with a partially filled d orbital.
  • Any element in the middle block of the periodic table
  • Any element whose 3d orbitals have a higher energy than the 4s orbitals
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8
Q

What is the electron configuration of titanium?

A

1s22s22p63s23p64s23d2

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9
Q

How do the transition metals compare to the alkali and alkaline earth metals?

A

Transition metals are harder and denser.

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10
Q

In most of the transition metals, the d orbitals fill up after the s orbitals of the next higher principal quantum number. Why does this occur?

A

Because the s orbitals have a lower energy

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11
Q

Transition metals form a variety of different charged cations. What is the most common charge on the cation formed by the transition metals?

A

2+

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12
Q

Metals are generally involved in the formation of which of the following?

A

Cations

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