C3.8 - Fullerenes and graphene Flashcards
Apart from diamond and graphite, there are what?
Apart from:
1. Diamond
2. Graphite
,there are other structures that carbon atoms can form
Apart from diamond and graphite, there are other structures that carbon atoms can form.
What happens in these structures?
In these structures, the carbon atoms join together to make large hollow cages
In these structures, the carbon atoms join together to make large hollow cages, which can have all sorts of shapes.
When was the ability of carbon to behave like this discovered?
The ability of carbon atoms to join together to make large hollow cages, which can have all sorts of shapes, was not discovered until 1985
The ability of carbon atoms to join together to make large hollow cages, which can have all sorts of shapes, was not discovered until 1985.
Radio astronomers had revealed what?
Radio astronomers had revealed that long chains of carbon atoms existed in outer space
The ability of carbon atoms to join together to make large hollow cages, which can have all sorts of shapes, was not discovered until 1985.
Radio astronomers had revealed that long chains of carbon atoms existed in outer space.
When scientists tried experiments in the lab to recreate the conditions that might account for these carbon chains, they created a new molecule by chance.
The molecule was made of 60 carbon atoms.
What did analysis show?
Analysis showed that:
- All the carbon atoms in the new molecule were equivalent
- There were no carbon atoms stuck at the ends of the molecule
The ability of carbon atoms to join together to make large hollow cages, which can have all sorts of shapes, was not discovered until 1985.
When scientists tried experiments in the lab to recreate the conditions that might account for long carbon chains that existed in outer space, they created a new molecule by chance, which was made of 60 carbon atoms.
Analysis showed that all the carbon atoms in the new molecule were equivalent.
There were no carbon atoms stuck at the ends of the molecule.
Who solved this problem?
Professor Sir Harry Kroto of Sussex University solved the problem
The ability of carbon atoms to join together to make large hollow cages, which can have all sorts of shapes, was not discovered until 1985.
When scientists tried experiments in the lab to recreate the conditions that might account for long carbon chains that existed in outer space, they created a new molecule by chance, which was made of 60 carbon atoms.
Analysis showed that all the carbon atoms in the new molecule were equivalent.
There were no carbon atoms stuck at the ends of the molecule.
Professor Sir Harry Kroto of Sussex University solved the problem by what?
Professor Sir Harry Kroto of Sussex University solved the problem by suggesting a structure of:
1. Hexagons
2. Pentagons
arranged in a sphere
When scientists tried experiments in the lab to recreate the conditions that might account for long carbon chains that existed in outer space, they created a new molecule by chance, which was made of 60 carbon atoms.
Professor Sir Harry Kroto of Sussex University solved the problem of all the carbon atoms being equivalent and no carbon atoms stuck at the ends of the molecule.
What happened since then?
Since then, scientists have made many other new molecules
When scientists tried experiments in the lab to recreate the conditions that might account for long carbon chains that existed in outer space, they created a new molecule by chance, which was made of 60 carbon atoms.
Professor Sir Harry Kroto of Sussex University solved the problem of all the carbon atoms being equivalent and no carbon atoms stuck at the ends of the molecule.
Since then, scientists have made many other new molecules.
How can they be shaped?
They can be shaped like:
- Footballs
- Rugby balls
- Doughnuts
- Onions
- Cones or tubes
Since Professor Sir Harry Kroto of Sussex University solving the problem of all the carbon atoms being equivalent and no carbon atoms stuck at the ends of the molecule, scientists have made many other new molecules.
They can be shaped like footballs (as in the spherical C60 molecules), rugby balls, doughnuts, onions (spheres within spheres) and cones or tubes (open or closed at the ends).
What is the general name for all these hollow-shaped molecules of carbon?
The general name for all these hollow-shaped molecules of carbon are fullerenes
Fullerene
A fullerene is a form of the element carbon that can exist as large cage-like structures, based on hexagonal rings of carbon atoms
What is the structure of fullerenes based on?
The structure of fullerenes is based on hexagonal rings of carbon atoms, as in graphite
The structure of fullerenes is based on hexagonal rings of carbon atoms, as in graphite.
However, what may they also have?
They may also have rings of:
1. 5 (pentagonal)
Or,
2. 7 (heptagonal) carbon atoms
What did the 1st fullerene to be discovered contain?
The 1st fullerene to be discovered contained 60 carbon atoms
The 1st fullerene to be discovered contained 60 carbon atoms, but what can chemists now do?
The 1st fullerene to be discovered contained 60 carbon atoms, but chemists can now make giant fullerenes that contain many 1000s of carbon atoms
Why was the name buckminsterfullerene chosen for the C60 molecule?
The name buckminsterfullerene was chosen for the C60 molecule after the Canadian architect Buckminster Fuller
The name buckminsterfullerene was chosen for the C60 molecule after the Canadian architect Buckminster Fuller.
What did Buckminster Fuller do in 1967?
Buckminster Fuller designed a similar shaped building of the C60 molecule in Montreal in 1967
Scientists have made many new molecules other than C60 that can be shaped like footballs (as in the spherical C60 molecules), rugby balls, doughnuts, onions (spheres within spheres) and cones or tubes (open or closed at the ends).
What can also be produced?
Cylindrical fullerenes called carbon nanotubes can also be produced
Scientists have made many new molecules other than C60 that can be shaped like footballs (as in the spherical C60 molecules), rugby balls, doughnuts, onions (spheres within spheres) and cones or tubes (open or closed at the ends).
Cylindrical fullerenes called carbon nanotubes can also be produced.
What do these fullerenes form?
These cylindrical fullerenes called carbon nanotubes form incredibly thin cylinders
Cylindrical fullerenes called carbon nanotubes form incredibly thin cylinders, whose length is much greater than their diameter.
What do they have?
These cylindrical fullerenes called carbon nanotubes have very useful properties, such as high:
- Tensile strength
- Electrical conductivity
- Thermal conductivity
One of the useful properties of cylindrical fullerenes called carbon nanotubes is high tensile strength.
What does this lead to?
High tensile strength leads to their use in reinforcing composite materials
One of the useful properties of cylindrical fullerenes called carbon nanotubes is high electrical conductivity and high thermal conductivity.
Why do cylindrical fullerenes have high electrical conductivity and high thermal conductivity?
Cylindrical fullerenes have high electrical conductivity and high thermal conductivity, because their bonding is like the bonding in graphite
Some fullerenes are what than buckminsterfullerene?
Some fullerenes are bigger spheres than buckminsterfullerene
Some fullerenes are bigger spheres than buckminsterfullerene.
Examples
For example:
- C240
- C540