Chapter 10 Flashcards

(27 cards)

1
Q

gases

A

-compressible, lots of space between molecules
-random motion, homogenous
kinetic energy is temp dependent
-collisions are purely elastic for IDEAL gases

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2
Q

volume

A

L=Liters

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3
Q

temperatrure

A

K=kelvin

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4
Q

pressure

A

atm=atmospheres

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5
Q

moles

A

n=mols

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6
Q

STP

A

if a gas is @ 1atm and 273K, one mol of that gas will occupy 22.4L

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7
Q

simple gas laws

A

always 2 sets of conditions changing, 2 sets of conditions that are constant (P,V,T,mols)

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8
Q

boyles law

A

P1V1=P2V2

@constant T and mols

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9
Q

charles law

A

V1/T1=V2/T2

@constant P and n

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10
Q

amonton’s law

A

P1/T1=P2/T2

@constant V and n

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11
Q

combined gas law

A

P1V1/T1=P2V2/T2

@constant moles

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12
Q

avogadros law

A

V1/n1=V2/n2

@constant P and T

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13
Q

ideal gas law (Rydberg Constant)

A

@STP=R=PV/nT (1atm(22.4L)/1mol(273K))
R= 0.082Latm/molK
PV=nRT

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14
Q

molecular mass ideal gas law

A

PV=mass/mmRT

mols=mass/molecular mass

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15
Q

density ideal gas law

A

P=dRT/mm

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16
Q

molarity ideal gas law

17
Q

dalton’s law of partial pressures

A

mixtures, each gas has its own partial pressure which contributes to the total pressure
Ptotal=Pgas1+Pgas2+Pgas3…
(Partial pressures)

18
Q

moles and pressure are ____ related to each other

A

directly

meaning that if you have more moles of gas you have a higher pressure of that gas

19
Q

if something says collected over water it means…

A

Ptotal=Pgas1+PH2O(g)

20
Q

mole fraction

A

Pgas1=Xgas1 Ptotal

21
Q

root mean square velocity

A
allows us to relate a gas to a specific root mean square as opposed to a distribution of velocities (V)
square root(3RT/mm)
mm=molecular mass
T=temperature in kelvin
R=8.134J/molK
22
Q

graham’s law

A

diffusion/effusion

23
Q

diffusion

A

how long it takes for a gas to be evenly distributed throughout a vessel

24
Q

effusion

A

similar but the vessel is segmented into two parts separated by a tiny hole

25
real gases (non-ideal gases)
(P+n2a/V)(V-nb)=nRT avalue=corrects for attractive forces since gas collisions are not purely elastic...corrects the pressure bvalue=corrects for the fact that gaseous molecules are 3D, take-up space, and have their own volume...corrects for the volume of vessel
26
a-value deviation (negative)
due to attraction forces CO2(g) dispersion (strong)
27
b-value deviation (positive)
due to atomic/molecular size of the gas