Chapter 10 Flashcards
(27 cards)
gases
-compressible, lots of space between molecules
-random motion, homogenous
kinetic energy is temp dependent
-collisions are purely elastic for IDEAL gases
volume
L=Liters
temperatrure
K=kelvin
pressure
atm=atmospheres
moles
n=mols
STP
if a gas is @ 1atm and 273K, one mol of that gas will occupy 22.4L
simple gas laws
always 2 sets of conditions changing, 2 sets of conditions that are constant (P,V,T,mols)
boyles law
P1V1=P2V2
@constant T and mols
charles law
V1/T1=V2/T2
@constant P and n
amonton’s law
P1/T1=P2/T2
@constant V and n
combined gas law
P1V1/T1=P2V2/T2
@constant moles
avogadros law
V1/n1=V2/n2
@constant P and T
ideal gas law (Rydberg Constant)
@STP=R=PV/nT (1atm(22.4L)/1mol(273K))
R= 0.082Latm/molK
PV=nRT
molecular mass ideal gas law
PV=mass/mmRT
mols=mass/molecular mass
density ideal gas law
P=dRT/mm
molarity ideal gas law
P=MRT
dalton’s law of partial pressures
mixtures, each gas has its own partial pressure which contributes to the total pressure
Ptotal=Pgas1+Pgas2+Pgas3…
(Partial pressures)
moles and pressure are ____ related to each other
directly
meaning that if you have more moles of gas you have a higher pressure of that gas
if something says collected over water it means…
Ptotal=Pgas1+PH2O(g)
mole fraction
Pgas1=Xgas1 Ptotal
root mean square velocity
allows us to relate a gas to a specific root mean square as opposed to a distribution of velocities (V) square root(3RT/mm) mm=molecular mass T=temperature in kelvin R=8.134J/molK
graham’s law
diffusion/effusion
diffusion
how long it takes for a gas to be evenly distributed throughout a vessel
effusion
similar but the vessel is segmented into two parts separated by a tiny hole