Chapter 8 Flashcards
(26 cards)
to ensure good reactivity…
SM’s need to be of the same phase
how do chemists ensure good reactivity
since molecules inherently have different phases, chemists dissolve molecules in solvents in order for all SM’s to be of the same phase (i.e. dissolved=aqueous)
solute
molecule that is being dissolved
solvent
molecule that is doing the dissolving process (dissolustion)…this is often H2O(l). for us, solvents will always be liquid
solution
solute and solvent create a solution
homogenous solution
is a mixture that cannot be determined to be a mixture visually
EX: NaCl (aq)=NaCl in water
heterogeneous solution
is a mixture that can be determined to be a mixture visually
EX: oil in water
ion-dipole forces of attraction
result when an ionic solid is dissolved in H2O
- Ionics in H2O result in electrolytic solutions (ones that conduct electricity due to ion dissociation)
- molecular compounds (not ionic) can still dissolve (matching of forces of attraction) but there is NO dissociation, the molecule solute is simply surrounded by solvent
- -result in non-electrolytic solutions
molarity
mols of solute/L of solution
molality
mols solute/kg of solvent
% mass
mass solute/total mass X100
% volume
volume solute/total volume solution X100
Aqueous reactions
1) acid-base reactions
2) precipitation reactions
3) redoc reactions
4) gas evolution reactions
Acid (bronsted-lowry definition)
is a source of H+ (aq) in aqueous solution
Base (bronsted-lowry definition)
source of hydroxide in aqueous solution (OH-; hydroxide)
acid-base chemistry
H+ (acid) + OH- (base)–>H2O
-results in a neutral charge=neutralization
titrations
used to quantitate concentrations of uknown solutions using quantitativereactions to ensure 100% reactivity of SM’s
precipitation reactions
not all ionic solutes are soluble in H2O(l), some precipitate out from H2O(l) giving rise to precipitation reactions
-solid precipitate produced from two aqueous SM’s
total ionic reaction
show all ions
net ionic reactions
just show the “players”, the ones doing the chemistry, not the “spectators”
redox reactions
reduction/oxidation reactions
1) identify oxidation #’s
2) write 1/2 reactions; one for oxidation and one for reduction using oxidation #’s as a guide
reduction
an element is gaining e-
oxidation
an element is losing e-
oxidation numbers
- if an element is in its natural state its oxidation number is ZERO
- in molecules, elements will have the same oxidation number as its prefered charge (for the most part) (use go to elements to aid in the process)
- the most electropositive elements get + oxidation numbers…greater elements
- most electronegative elements get - oxidation number
- the sum of the oxidation # in a molecule must equal the charge on the molecule