Chapter 2 (pt 2) Flashcards
(21 cards)
schrodinger equation
- different for every element due to different # in protons
- relates to energy
- Equation=E=-2.18x10^-18(1/n^2) where n=principle quantum number and is the shell #
- used when describing an energy relationship of e- as a result from the equation above
electrons closest to the nucleus have the ____ coulombic attraction
greatest
energy levels of electrons
-the energy increases (gets more positive) with shells while the coulombic attaraction decreases (n=1,2,3,4,…)
color and electronic transition
consists of an electron getting excited (excitation) and then relaxing (relaxation) resulting in a photon. When the electron relaxes and creates a photon is when the color appears.
excitation
electron goes from lower energy n-level to a higher energy n-level
relaxation
electron goes from higher energy n-level to a lower energy n-level
atoms like to be at the ____energy possible
lowest
exothermic
when energy is flowing out of something, it is negative
endothermic
when energy is flowing into somehting, it is positive
quantum numbers
describe an e-‘s emergy, shape of orbit, probability of being found, and spin
n
n=the principle quantum number (energy)
l
- angular momentum quantum number (shape of orbit)
- describes how the orbits are distributed/what they look like
- has a range of values from 0 to n-1
l=0
s-orbital (sphere shaped)
l=1
p-orbital (dumbell shape)
l=2
d-orbital (clover leaf shape)
l=3
f-orbital (complex)
ml
magnetic quantum number (how many of each orbital you actually have)
- a range of values from -l to 0 to +l (-1 0 +1)
- depending on the magnetic field there are different orientations of l that result
when l=0 ml=?
ml=0
- 1 orbital ever in a l=0 or s-orbital
- means there is only ever one s-orbital per principle quantum level
when l=1 ml=?
ml=-1, 0, +1
-3 orbitals ever in a l=1 or p-orbital set
means that there is always three p-orbitals per principle quantum level
when l=2 ml=?
ml=-2, -1, 0, +1, +2
-5 orbitals ever in a l=2 or d-orbital set
means there are always 5 d-orbitals per principle quantum level
when l=3 ml=?
ml=-3, -2, -1, 0, +1, +2, +3
- 7-orbitals for l=3 or f-orbital set
- means there are always seven f-orbitals per principle quantum level