Chapter 6 Flashcards
(11 cards)
hybridization
a mash-up of valence orbitals to have unpaired valence e- in proper orientations for bonding (minimizing e-/e- repulsions)
3 group hydridization
sp2
4 group hybridization
sp3
5 group hybridization
dsp3
6 group hybridization
d2sp3
sigma bond
is a single bond (first connection) and is always a result from hydridized orbitals
pi bonds
is the extra layer of bonding (past the single bond) to create double and triple bonds, these always result from non-hybridized orbitals
double bonds consists of…
1 sigma and 1 pi bonds
triple bonds consists of…
1 sigma and 2 pi bonds
linear combinations of atomic orbitals/molecular orbital theory (MO theory)
- describes the energetics of bonding between elements
- all orbitals are combined between two elements. Each combination of 2-orbitals results in 2 new orbitals, a bonding orbital (good) and an antibonding orbital (bad)
bond order
predicts if a molecule can exist
BO=0 molecule cannot exist
BO>0 molecules can exist
Formula: # of e- in bonding-#of e- in antibonding/2