Chapter 6 Flashcards

(11 cards)

1
Q

hybridization

A

a mash-up of valence orbitals to have unpaired valence e- in proper orientations for bonding (minimizing e-/e- repulsions)

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2
Q

3 group hydridization

A

sp2

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3
Q

4 group hybridization

A

sp3

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4
Q

5 group hybridization

A

dsp3

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5
Q

6 group hybridization

A

d2sp3

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6
Q

sigma bond

A

is a single bond (first connection) and is always a result from hydridized orbitals

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7
Q

pi bonds

A

is the extra layer of bonding (past the single bond) to create double and triple bonds, these always result from non-hybridized orbitals

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8
Q

double bonds consists of…

A

1 sigma and 1 pi bonds

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9
Q

triple bonds consists of…

A

1 sigma and 2 pi bonds

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10
Q

linear combinations of atomic orbitals/molecular orbital theory (MO theory)

A
  • describes the energetics of bonding between elements
  • all orbitals are combined between two elements. Each combination of 2-orbitals results in 2 new orbitals, a bonding orbital (good) and an antibonding orbital (bad)
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11
Q

bond order

A

predicts if a molecule can exist
BO=0 molecule cannot exist
BO>0 molecules can exist
Formula: # of e- in bonding-#of e- in antibonding/2

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