Module 1: Introduction to Organic Chemistry Flashcards

1
Q

Organic chemistry is the study of compounds containing

A

Carbon

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2
Q

Of the more than 37 million presently known chemical compounds, more than ____ of them contain carbon

A

99%

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3
Q

Carbon can share

A

four valence electrons

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4
Q

Carbon can share FOUR valence electrons and form four strong

A

covalent bonds

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5
Q

Carbon can share FOUR valence electrons and form four strong covalent bonds (which can either be single, double, or triple bond), forming a stable

A

tetrahedral geometry

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6
Q

Carbon bonds readily with itself, forming chains

A

polymerism

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7
Q

Can also produce compounds with the same number of atoms but different structures

A

isomerism

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8
Q

There are three generally accepted sources of organic compounds

A

carbonized organic matter
living organisms
invention/human ingenuity

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9
Q

It is the study of compounds containing carbon, both naturally occurring and synthetic compounds

A

Organic chemistry

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10
Q

Any atom that is not carbon or hydrogen is called a

A

heteroatom

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11
Q

examples of heteroatom

A

N, O, S, P and halogens

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12
Q

Compounds with Carbons that are Inorganic

A

carbonate (CO32-)
cyanide (CN-)
bicarbonate (HCO3-)
carbon dioxide (CO2)
carbon monoxide (CO)

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13
Q

Remember that organic compounds are compounds that were either ________________ or derived from something that was ______________, or they can be _______________.

A

once-living
once living
synthesized

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14
Q

often flammable

A

organic

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15
Q

non-flammable

A

inorganic

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16
Q

usually covalent

A

organic

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17
Q

often ionic

A

inorganic

18
Q

based on C

A
19
Q

organic

A

not based on C (Sometimes contain carbon but not C-H bonds)

20
Q

low BP and MP

A

organic

21
Q

high BP and MP

A

inorganic

22
Q

derived from living or once-living matter

A

organic

23
Q

minerals and ores

A

inorganic

24
Q

In the ______, organic compounds are believed to have originated from living organisms, and only living things could synthesize

A

1800’s

25
Q

“We cannot prepare organic compounds in the laboratory because ‘vital force’ is absent there.”

A

Jons Jacob Berzelius

26
Q

However, in ________, Friedrich Wöhler discovered that urea

A

1828

27
Q

However, in 1828, ________________________ discovered that urea

A

Friedrich Wöhler

28
Q

However, in 1828, Friedrich Wöhler discovered that urea, an organic compound, could be made by heating the inorganic compound ______________________

A

ammonium cyanate

29
Q

“The great tragedy of science, the slaying of a beautiful hypothesis by an ugly fact.”

A

Friedrich Wöhler

30
Q

In the 20th century, organic chemistry branched into sub-disciplines such as

A

polymer chemistry
pharmacology
bioengineering
petrochemistry

31
Q

date: morphine extracted from opium poppy

A

1804

32
Q

date: aspirin commercialization

A

1899

32
Q

date: discovery of penicillin

A

1928

33
Q

date: use of tubocurarine as anaesthetic

A

1942

34
Q

date: vinca alkaloids, cancer treatment

A

1963

35
Q

date: taxol discovery

A

1971

36
Q

date: artemisinin discovery

A

1972

37
Q

date: captopril approval for hypertension treatment

A

1981

38
Q

lovastatin approved as lipid-lowering agent

A

1987

39
Q

date: prialt ziconotide, oseltamivir tamiflu

A

2000