ProsthoMat Flashcards
(130 cards)
Eugenol effect?
eugenol is extracted from?
obtundent effect / relief
from oil of cloves
more stable technique to soften the impression compound
dry heat - best for the material
water bath - more convenient, best for patient and dentist
elastic impression material with the least tear strength
Hydrocolloids
(reversible > irrev)
ability of material to change its form based on temperature
Hysteresis - only seen in reversible hydrocolloids (agar)
a. Liquefaction - gel to sol (boiling)
b. gelation - sol to gel
*imbibition - absorbs water
syneresis - releases water
components of reversible hydrocolloids? principal component
water (85%) - principal
agar (15%) (sometimes w/ borax)
effect of borax to dental materials
+gypsum = retarder
+agar = hardener
least dimensionally stable impression material, shortest setting time and least expensive
irreversible hydrocolloids (alginate)
components of irreversible hydrocolloids? principal component? major component?
sodium alginate/potassium alginate - reactor (major)
calcium sulfate - reactor
diatomaceous earth/silica - filler (50~% principal component)
sodium phosphate - retarder
ways to decrease setting time of alginate
increase water temp
mix rapidly
decrease water to powder ratio (thicker consistency)
1st elastomer (3 names)
polysulfide, mercaptan, thiokol
Composition of polysulfide
BASE - white
liquid poly sulfide polymer 80-85%
fillers - carbonate, silica, titanium dioxide, zinc sulfate, copper
ACCELERATOR - brown/gray
lead dioxide - 60-68% (an alternative will be hydroperoxide)
dibutyl phthalate - 30-35%
sulfur - 3%
others - 2%
lead dioxide causes stain and foul odor
characteristics of polysulfide
longest setting time (12 mins) foul odor in not usually tolerated
messy to work with (viscous and sticky)
stains and emits foul odor (lead dioxide)
greatest tear strength
hydrophobic
least dimensionally stable among the elastomers
condensation silicones / conventional silicones
Characteristics of condensation silicone
has a byproduct - ethyl alcohol –> can cause shrinkage
pleasant odor
hydrophobic
least dimensionally stable among the elastomers
composition of condensation silicone
BASE
polydimethyl siloxane
colloidal silica / metal oxide filler - 35 -75 %
ACCELERATOR
orthoethyl silicate - cross linking agent
stannous octoate - catalyst
composition of addition silicone (PVS)
BASE
poly (methyl hydrogen siloxane)
fillers
prepolymers
ACCELERATOR
divinyl polysiloxane
platinum salt - catalyst (chloroplatinic acid)
palladium - hydrogen absorber
retarders
fillers
characteristics of addition silicone
pleasant odor
excellent reproduction details
most dimensionally stable (up to 2 weeks)
hydrophobic
emits hydrogen gas
avoid latex gloves (contains sulfur) –> retards setting
plasticizer of polyether
glycoether or phthalate
cross linking agent of polyether? condensation silicone?
P - aromatic sulfonate ester
CS - orthoethyl silicate
characteristics of polyether
extremely stiff
very difficult to remove from mouth
hydrophilic
best compatibility with stone
very expensive
rank dimensional stability of elastomers
Addition silicone > polyether > polysulfide > condensation silicone
types of gypsum
type 1 - impression plaster
type 2 - dental plasters
type 3 - dental stone
type 4 - improved stone (die stone)
type 5 - high strength dental stone, high expansion
how is gypsum manufactured?
heating gypsum loses part of its water
calcium sulfate dihydrate –> calcium sulfate hemihydrate
calcination
differentiate the two hemihydrates
plaster - open kettle >100C - irregular particles, porous
stone - closed kettle or steamed under pressure > 100C - regular particles (prismatic), lesser porosity (denser)