Exam 2 final review Flashcards

(56 cards)

1
Q

carbonyl group is at end of the carbon chain

A

aldose

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2
Q

carbonyl group is at any other position (in a ketone group)

A

ketose

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3
Q

pentose. component of RNA and comp of DNA

A

Rna: d - ribose DNA: 2-deoxy-d-ribsoe

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4
Q

2 hexoses are what

A

d-glucose, d-fructose

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5
Q

chiral center most instant from carbonyl carbon

A

reference carbon

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6
Q

two sugars that differ only in the configuration around one carbon atom

A

epimer

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7
Q

epimers of glucose

A

mannose, galactose

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8
Q

6 membered ring, form when the hydroxyl group at C5 reacts with the aldehyde group at C1

A

pyranoses

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9
Q

5 membered ring, form when the hydroxyl group at C5 reacts with the keto group at C2

A

furanoses

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10
Q

function of amylose

A

energy storage in plants

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11
Q

function of amylopectin

A

energy storage in plants

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12
Q

glycogen function

A

energy storage in bacteria and animal cells

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13
Q

cellulose function

A

structural in plants, gives rigidity and strength to cell walls

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14
Q

chitin function

A

structural in insects, spiders, gives rigidity and strength to exoskeletons

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15
Q

peptidoglycan function

A

structural in bacteria, gives rigidity and strength to cell envelope

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16
Q

dominant surface feature of the outer membrane of gram negative bacteria

A

lipopolysaccharides

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17
Q

serve as main target for our immune system

A

lipopolysaccharides

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18
Q

3 functions of phosphorylation

A

traps biomolecule, activates biomolecule, contributes to binding energy

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19
Q

2 phases of glycolysis

A

prepatory and payoff

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20
Q

relationship between k and delta g is

A

delta G = -RT ln (k)

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21
Q

when k is less than 1, the reaction…

A

proceeds in reverse

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22
Q

when k is more than 1, the reaction..

A

proceeds forward

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23
Q

Mg2+ in the cytosol binds to….

24
Q

how is pyruvate formed

A

PEP is hydrolyzed

25
have a sulfer atom that has replaced the oxygen in the ester bond
thioesters
26
conjugate redox pair includes what
something reduced, something oxidized
27
reaction where a compound loses two electrons and two hydrogen ions
dehydrogenation
28
dehydrogenation catalyzed by what
dehydrogenases
29
what do NAD+ and NADP+ both accept
two electrons, one proton
30
coenzymes derived from the vitamin riboflavin
flavin nucleotides
31
enzymes that contain flavin nucleotides
flavoproteins
32
under aerobic conditions, pyruvate is...
oxidized to acetyl CoA
33
under anaerobic condones, pyruvate is...
reduced to lactate or ethanol
34
effect by which the rate and total amount of glucose consumption under anaerobic conditions is many times greater than under aerobic conditions
Pasteur effect
35
observation that tumor cels have high rates of glycolysis , with fermentation of glucose to lactate, even in the presence of oxygen
Warburg effect
36
general term for processes that extract energy as ATP, but do not consume oxygen or change the concentrations of NAD+ or NADH
fermentation
37
pyruvate accepts electrons from NADH and is reduced to lactate while regeneration the NAD+ necessary for glycolysis
lactic acid fermentation
38
pyruvate is further catabolized to ethanol
ethanol fermentation
39
terminal election acceptor in lactic acid fermentation
pyruvate
40
organisms can regenerate NAD+ by transferring electrons from NADH to pyruvate,, forming....
lactate
41
catalyzed the reduction of pyruvate to lactate
lactate dehydrogenase
42
erythrocytes, renal medulla, brain and sperm all require what
glucose
43
mitochondrial enzyme that converts pyruvate to oxaloacetate
pyruvate carboxylase
44
pyruvate carboxylase requires what coenzyme
biotin
45
mitocondrial enzyme that uses NADH to reduce oxaloacetate to malate
malate dehydrogenase
46
malate is reoidized to oxaloacetate in what
cytosol
47
converts fructose 1,6 bisphosphate to fructose 6 phosphate by hydrolysis of the C-1 phosphate
fructose 1, 6 bisphosphate
48
catalyzed the simple hydrolysis of glucose 6 phos to glucose
glucose 6 phosphatase
49
glucokinase is also known as
hexokinase 4
50
if there is low ATP, how does this affect PFK1 binding
higher affinity
51
ADP and AMP do what to PFK1
increase it
52
citrate and ATP do what to PFK1
inhibit
53
F26BP does what
activates PFK1, inhibits FBPase 1
54
catalyzes formation of fructose 2,6-bisphosphate
phosphofructokinase 2
55
catalyzed the breakdown of fructose 2,6 bisphosphate
fructose 2,6 bisphosphatase
56
alternative pathway for glucose oxidation
pentose phosphate pathway