ORGANiC MOLECULES(carbohydrates) Flashcards

(31 cards)

1
Q

why are carbohydrates the most abundant organic molecules

A

because of the abundance of photosynthetic organisms like plants and algae

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2
Q

essential proteins

A

proteins that cannot be coded for by our DNA and should therefore be consumed in our diet

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3
Q

what is the essence of flavin nucleotides?

A

they are important for oxidation-reduction reactions

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4
Q

when in a protein structure, amino acids are referred to as

A

residues

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5
Q

what are blood group distinctions between certain people due to

A

specific sugars on the red blood cells

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6
Q

how are carbohydrates classified?

A

based on the;
number of sugars present
number of carbon atoms
the functional group

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7
Q

carbohydrates with between 3-10 sugars present

carbohydrates with more than 10 sugars present

A

Oligosaccharides

polysaccharides

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8
Q

how are monosaccharides numbered?

A

numbered beginning at the end that contains the carbonyl carbon

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9
Q

The general formula of carbohydrates

A

(CH20)n
n represents the number of carbon atoms

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10
Q

aldoses

ketoses

A

carbohydrates with the carbonyl group at the end of the molecule

carbohydrates with the carbonyl group elsewhere in the molecule

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11
Q

isomers

A

compounds with the same chemical(molecular) formula but different structures

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12
Q

constitutional isomers

A

they differ in the order of attachment of atoms

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13
Q

diastereoisomers

the two classifications of diastereoisomers

A

isomers that are not mirror images of each other

epimers and anomers

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14
Q

epimers

anomers

A

carbohydrate isomers that only differ in configuration around one specific carbon
atom(with the exception of the carbonyl carbon atom)

isomers that differ on a new asymmetric carbon formed on ring closure

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15
Q

pyran

A

a six-membered ring

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16
Q

difference between alpha and beta glucose

A

the hydroxyl group is below the carbon 1 atom in an alpha glucose molecule and above it in a beta glucose molecule

17
Q

when is acyclic monosaccharide considered
alpha
beta

A

when the CH2OH(containing carbon 6) group is opposite the hydroxyl group

when the CH2OH(containing carbon 6) group is on the same side as the hydroxyl group

18
Q

furan

A

a five-membered ring

19
Q

anomeric carbon

A

after cyclization, the former carbonyl carbon is referred to as the anomeric carbon

20
Q

for a monosaccharide enantiomer to be considered as D or L, which carbon should be considered

when is the enantiomer considered a D
when is the enantiomer considered a L

A

carbon 5

when the OH group is on the right of carbon 5
when the OH group is on the left of carbon 5

21
Q

the bond that links monosaccharides is known as?
which enzymes catalyze the formation of this bond?

A

Glycosidic bond

glycosyltransferases

22
Q

what are the monosaccharides that make up the following up the following;
lactose

maltose

sucrose

A

beta galactose and alpha glucose

alpha glucose and alpha glucose

alpha glucose and beta fructose

23
Q

are all monosaccharides reducing sugars? why?

A

yes
because the hydroxyl group on the anomeric carbon is not linked to any other molecule, so it can be an open ring

24
Q

the storage form of glucose in animals

25
GLYCOGEN subunits bonds branches ?
alpha glucose 1-4 and 1-6 glycosidic bonds yes, there is a branch after every ten subunits
26
CELLULOSE subunits bonds branches?
beta glucose 1-4 glycosidic bonds no
27
STARCH FORMS? AMYLOSE subunits bonds branches? AMYLOPECTIN subunits bonds branches?
two, amylopectin and amylose alpha glucose 1-4 glycosidic bonds no alpha glucose 1-4 and 1-6 glycosidic bonds yes, there are branches after every 20 subunits
28
which between amylopectin and glycogen is able to store more energy and why
glycogen, as it is more compact due to there being more branches
29
If the hydroxyl group on the anomeric carbon in a cyclic monosaccharide is not linked to another compound, then what happens?
the ring can open, and the sugar can therefore act as a reducing agent, thereby the name reducing sugars.
30
in complex carbohydrates, If the group on the non-carbohydrate molecule to which the sugar is attached is an –NH2 group, then what name is given to; the structure formed the bond formed If the group on the non-carbohydrate molecule to which the sugar is attached is an OH group, the what name is given to; the structure the bond formed
N-glycoside N- glycosidic link O-glycoside O-glycosidic link
31