Midterm - Carbohydrates Flashcards

1
Q

stereoisomers

A

same molecular formula and sequence but differ in 3D space due to chiral carbon atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

enantiomer

A

mirror image

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

diastereomers

A

not a mirror

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

D - configuration

A

last OH group on the right

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

L-configuration

A

last OH group on the left

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

how to determine the number of stereoisomers for a molecule

A

2^n
where n = # chiral carbons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

why are D-monosaccharides nutritionally important

A

digestive enzymes are stereospecific for D sugars

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

hemiacetal

A

made from aldose

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

hemiketal

A

made from ketose

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

what is the most common oligosaccharide

A

disaccharides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

what are two types of polysaccharides

A

homopolysaccharides
heteropolysaccharides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

which is more abundant in food

A

homopolysaccharides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

what polysaccharide is rich in plants

A

starch (amylose, amylopectin)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

what polysaccharide is rich in animal

A

glycogen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

what kind of fibre is cellulose

A

both a dietary and a functional fibre

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

what is cellulose

A

homopolysaccharide of B-1,4 glucose units

17
Q

health benefits of fibre

A

maintains function and health of gut
decreases constipation
increases satiety

18
Q

3 fates of glucose in a cell

A
  1. enters glycogenesis for energy storage
  2. enters glycolysis for energy production
  3. enters hexose monophosphate shunt to generate precursors for biogenesis
19
Q

what does the use of glucose depend on

A

the cell and its requirements at the time

20
Q

glycogenin

A

enzyme that serves as a scaffold on which to attach glucose molecules to build glycogen (primer)

21
Q

how many glucose molecules can be contained in a single glycogen structure

A

30,000+

22
Q

what do insulin and glucagon work to maintain

A

blood glucose homeostasis

23
Q

when does the cori cycle occur

A

anaerobic state

24
Q

what is the hexose monophosphate shunt important for

A

NADH production and ribose synthesis

25
Q

where does the hexose monophosphate shunt occur

A

cytoplasm

26
Q

what is the hexose monophosphate shunt used to generate

A

NADPH and precursors for nucleotide synthesis

27
Q

what is the total amount of energy from 1 molecule of glucose

A

38 ATP

28
Q

when is gluconeogensis active

A

when glucose is needed in the body

29
Q

what are nearly all monosaccharides taken up by

A

enterocytes

30
Q

what is the transport of glucose to galactose from lumen to blood dependent on

A

basolateral Na-K ATPase activity

31
Q

what is fructose taken up by

A

facilitated transport

32
Q

how do glucose, galactose and fructose all enter blood

A

via GLUT2

33
Q

what is the primary source of energy for cells

A

glucose

34
Q

what do carbs spare

A

protein (prevents protein breakdown)

35
Q

what do carbs prevent

A

ketosis

36
Q

what occurs when carbs are limited

A

fats get broken down for energy, producing ketone bodies and causing blood to become acidic