Structure 2.2.4 - VSEPR model Flashcards
June 2 (17 cards)
What are electron domains responsible for
molecular geometry (shape)
what does the electron domain include
the # of lone pairs of electrons, as well as any single or double or triple bonds
What does VSEPR stand for
Valence shell electron pair repulsion model
Types of electron domains
-lone pair of electrons (non-bonding domains) (except in the case of a coordination bond)
-bonding domain (single, double, or triple bond)
What determines the molecular geometry
the total # of domains
-the geometry hence depends on the repulsion b/w domains
non bonding vs bonding domains, which exert the greatest repulsive force and why
non bonding (lone pairs), due to charge density
repulsive force in triple, double, single bonds and why
Triple> double > single for repulsive force, as electron density decreases
angle of a bent geometry
104.5
angle of trigonal pyramidal
107
angle of a tetrahedral geometry
109.5
angle of a trigonal planar
117
molecule geometry vs E- domain geometry of a species w 3BD and 1 NBD
molecule geometry=trigonal pyramidal
E- domain geometry= tetrahedral
molecule geometry vs E- domain geometry of a species w 2BD and 2 NBD
Molecule geometry=bent
E- domain= tetrahedral
molecule geometry vs E- domain geometry of a species w 4BD and 0 NBD
molecule geom-tetrahedral
e domain- tetrahedral
molecule geometry vs E- domain geometry of a species w 3BD and 0 NBD
molecule geom-trigonal planar
e- domain geom- trigonal planar
molecule geometry vs E- domain geometry of a species w 2BD 0NBD
molecule geom-linear
e- domain geom-linear
molecule geometry vs E- domain geometry of a species w 2BD and 1 NBD
Molecule Geom- V shaped
e- domain geom- trigonal planar