Bonding Flashcards

(52 cards)

1
Q

n Quantum number stands for

A

Principal quantum number

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2
Q

Principal quantum number means

A

Energy level of an e-

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3
Q

Is a smaller energy level higher or lower energy?

A

Lower

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4
Q

Is a smaller energy level closer to or further from the nucleus

A

Closer to

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5
Q

l Quantum number stands for

A

Azimuthal quantum number

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6
Q

Azimuthal quantum number means

A

Subshell (s, p, d…)

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7
Q

l=0 means

A

S e-

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8
Q

l=1

A

P e-

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9
Q

l=2

A

D e-

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10
Q

l=3

A

F e-

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11
Q

ml Quantum number means

A

Magnetic quantum number

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12
Q

Magnetic quantum number means

A

Orbital shape

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13
Q

What is the probability of an e- being at a node?

A

0%

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14
Q

ms Quantum number means

A

Spin quantum number

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15
Q

Spin quantum number means

A

Which e- in the orbital

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16
Q

Values of ms

A

+ and - 1/2

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17
Q

Values of ml

A

-l to l

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18
Q

Values of l

A

0 to n-l

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19
Q

Values of n

A

1 to infinity

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20
Q

How do molecular orbitals form?

A

When two atomic orbitals combine

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21
Q

Is a bonding or antibonding MO higher in energy?

22
Q

Is a bonding or antibonding MO higher more stable?

23
Q

How does a bonding MO form?

A

Sign of the wave functions of the atomic orbitals is the same

24
Q

How does an antibonding MO form?

A

Sign of the wave functions of the atomic orbitals is different

25
How many electrons form a sigma bond?
Two
26
What bonds do single bonds contain?
Sigma
27
What do head to head or tail to tail overlaps create?
Sigma bonds
28
Can sigma bonds exist without pi bonds?
Yes
29
Can pi bonds exist without sigma bonds?
No
30
What do double bonds contain?
One sigma and one pi bond
31
What do triple bonds contain?
One sigma and two pi bonds
32
What causes higher order bonds to rotate less than single bonds?
Pi bonds
33
Is a sigma or pi bond stronger?
Sigma
34
Is a double or triple bond stronger?
Triple
35
Is a single or double bond longer?
Single
36
What is the relationship between bond order, length, and strength?
Increasing bond order is increasing strength and decreasing length
37
What is hybridization?
Mixing of different types of orbitals
38
What is s character of sp3?
25%
39
What is s character of sp2?
33%
40
What is s character of sp?
50%
41
What shape does sp3 take?
Tetrahedron
42
What are bond angles of sp3?
90 degrees
43
What are bond angles of tetrahedron?
90 degrees
44
What are bond angles of sp2?
120 degrees
45
What shape does sp2 take?
Trigonal planar
46
What are bond angles of trigonal planar?
120 degrees
47
What are bond angles of sp?
180 degrees
48
What are bond angles of linear?
180 degrees
49
What shape does sp take?
Linear
50
What orbital hybridization forms pi bonds?
Unhybridized p orbitals
51
What is resonance delocalization of electrons?
Alternating single and multiple bonds with a backbone of unhybridized p orbitals which causes delocalization of pi electrons and stabilization of a molecule
52
What are alternating single and multiple bonds called?
Conjugated pi system