Oligosaccharides & Polysaccharides Flashcards

1
Q

Define oligosaccharides.

A

A condensation product of 3-10 monosaccharides

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2
Q

True or False:

Most oligosaccharides are not digested by human enzymes

A

True

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3
Q

What is another name for raffinose? What is it?

A

Melitose

Trisaccharide

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4
Q

Define polysaccharide

A

high molecular weight polymers

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5
Q

Most carbs found in nature occur as

A

polysaccharides

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6
Q

Polysaccharides are

A

large molecules of monosaccharides that are connected to each other through their anomeric carbons

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7
Q
  1. Polysaccharides are condensation products of _____

2. They can be ______ or _____

A

more than 10 monosaccharide units

linear or branched

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8
Q

3 biologically important polysaccharides are:

A

starch, glycogen, and cellulose

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9
Q

All 3 (biologically important polysaccharides) are ________ but they differ in the type of ______ ______ and/or the amount of ________

A

polymers of D-glucose
glycosidic bond
branching

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10
Q

How do polysaccharides differ from each other?

A
  • identity of their monosaccharide units
  • length of their chains
  • types of bonds linking the units
  • degree of branching
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11
Q

What are polysaccharides classified into?

A

homopolysaccharides

heteropolysaccharides

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12
Q

Homopolysaccharides

A

when polysaccharides are composed of a single type of monosaccharide building block

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13
Q

Heteropolysaccharides

A

polysaccharides composed of more than 1 type of monosaccharide

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14
Q

Examples of Homopolysaccharides

A

starch
glycogen
cellulose
dextrins

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15
Q

Heteropolysaccharides can be divided into

A

glycoseaminoglycans and mucilages

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16
Q

Examples of glycoseaminoglycans

A

hyluronic acid
heparin
ABO blood

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17
Q

Examples of Mucilages

A
  • agar
  • pectins
  • hemicellulose
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18
Q

Starches and dextrins ( polysaccharides)

A
  • digested by human enzymes

- its hydrolysis provide glucose (the most important carb)

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19
Q

Nonstarches (polysaccharides)

A

not digested by human enzymes and are the major component of dietary fiber

20
Q

What are the 2 types of polysaccharides?

A

storage polysaccharides

structural polysaccharides

21
Q

Storage and structural polysaccharides are made up of _______ _____, but they are _________ and ________ different

A

glucose units

structurally and functionally

22
Q

Storage polysaccharides

Name 3

A

contain only a-glucose units

3 important ones are starch, glycogen, and amylopectin

23
Q

Structural polysaccharides

Name 2

A

contain only B-glucose units

2 important ones are cellulose and chitin

24
Q

Chitin contains a

A

modified B-glucose unit

25
Q

Function of Starch

A

the main storage form of glucose in plant cells

26
Q

Structure of Starch

A

its structure is identical to glycogen except for a much lower degree of branching (ab every 20-30 residues)

27
Q

Pure starch is …………
Powder that is ………
Found in ………..
Gives blue color with ………..

A

white, tasteless, and odorless
insoluble in cold water
wheat, rice, corn, potatoes
iodine

28
Q

What is amylose?

A

a glucose polymer with a(1–>4) linkages

29
Q

What is amylopectin?

A

a glucose polymer with mainly a(1–>4) linkages, but it also has branches formed by a(1–>6)

30
Q

Function and Location of Glycogen

A
  • a storage polysaccharide found in animals

- stored in the liver and muscles

31
Q

Structure of Glycogen

A

its structure is identical to amylopectin, except that a(1–>6) branching occurs about every 12 glucose units

32
Q

When glucose is needed, glycogen is

A

hydrolyzed in the liver to glucose

33
Q

Function of Cellulose

A

the main constituent of the plant’s cell wall

34
Q

Cellulose is

A

insoluble

35
Q

Structure of Cellulose

A

a polysaccharide consisting of a linear chain of several hundred to over 10 thousand B (1–>4) linked B-D-glucose units

36
Q

Why can some animals digest cellulose? Which animals?

A

some animals can digest cellulose with the help of bacteria in their stomachs
-ruminants and termites

37
Q

How do human digest cellulose?

A

we do NOT have the enzymes needed to digest the bonds in fibers

38
Q

What can cellulose be called?

What does it act as?

A

dietary fiber

acts as a hydrophilic bulking agent for feces

39
Q

What inulin?

Where is it found?

A
  • It’s a polysaccharide of fructose

- its found in tubers and roots of some plants, readily soluble in water

40
Q

What can inulin be used for?

A

determining the glomerular filtration rate

41
Q

Can inulin be hydrolyzed by intestinal enzymes?

A

no

42
Q

What are the fructose units in inulin joined by?

A

a B (2–>1) glycosidic bond

43
Q

In general, plant inulin polymers contain between

A

20 and several thousand fructose units

44
Q

What is chitin?

What is composed of?

A
  • is a structural polysaccharide found in the exoskeleton of insects
  • composed of N-acetylglucoseamine units linked by B1–>4 bond
45
Q

What is dextrin?

A

the intermediate in the hydrolysis of starch