Biochemistry Chapter 2-AP Bio Part 2 Flashcards

(71 cards)

0
Q

What are periods, and what do they correspond to?

A

The rows of the periodic table, corresponds to the number of electron shells in their atoms.

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1
Q

What is the chemical behavior of an atom determined by

A

The distribution of electrons in the atom’s electron shells.

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2
Q

What does the left to right sequence of elements corresponds to _______________

A

The sequential addition of electrons and protons

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3
Q

All matter prefers to exist on what state of energy

A

Lowest available state of potential energy-first shell.

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4
Q

What does the chemical behavior of atoms depend on

A

The number of electrons in its outermost shell.

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5
Q

Valence electrons

A

Electrons in the outermost shell

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6
Q

Valence shell

A

The outermost shell of electrons.

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7
Q

An atom with a complete outside shell is

A

Unreactive

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8
Q

Inert

A

Chemically unreactive (noble gases)

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9
Q

Each concentric circles in an atom diagram represents

A

The average distance between an electron in that shell and the nucleus

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10
Q

Orbital

A

The 3D space where an electron is found 90% of the time

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11
Q

Describe the orbital(s) of the first electron shell

A

Only one spherical orbital ( called 1s)

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12
Q

Describe the orbital(s) of the second shell

A

There are 4. One large spherical s orbital (2s). And 3 dumbbell shaped p orbitals (called 2p orbitals).

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13
Q

Describe the orbital(s) for the 3rd shell and higher

A

Have s and p orbitals as well, and orbitals of more complex shapes.

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14
Q

How many electrons can occupy an orbital

A

No more than 2

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15
Q

The reactivity of an atom arises from what

A

The presence of unpaired electrons in one or more orbitals of its valence shell.

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16
Q

Which electrons are involved in the atoms interacting with valence shells

A

Unpaired electrons

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17
Q

Chemical bonds

A

Atoms held close together due to sharing or transferring valence electrons

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18
Q

Covalent bond

A

The SHARING of a pair of valence electrons by 2 atoms.

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19
Q

How do atoms have the ability to share electrons

A

The hydrogen atoms come close enough for their 1s orbitals to overlap.

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20
Q

Molecule

A

2 or more atoms held together by covalent bonds

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21
Q

Molecular formula

A

H2, incites the molecule consists of 2 hydrogen atoms

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22
Q

Lewis dot structure

A

Element symbols are surrounded by dots that represent the valence electrons. (H:H)

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23
Q

Structural formula

A

H—H, the line represents a single bond

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24
Single bond
A pair of shared electrons
25
Double bond
Sharing of 2 pairs of valence electrons (o=o).
26
Each atom that can share valence electrons has
a bonding capacity corresponding to the number of covalent bonds the atom can form.
27
Valence
The bonding capacity of an atom, usually equals the number of unpaired electrons required to complete the atoms valence shell.
28
What's the main component of natural gas
Methane
29
Electronegativity
The attraction of a particular atom for the electrons of a covalent bond.
30
The more electronegative an atom is ______________
The more strongly it pulls shared electrons toward itself.
31
In a caovalent bond between 2 atoms of the same element
The electrons are shared equally because the 2 atoms have the same electronegativity.
32
No polar covalent bond
Electrons in a covalent bond are shared equally because they have the same electronegativity. (Same element)
33
Polar covalent bond
When an atom is bonded to a move electronegative atom, the electrons of the bond are not shared equally. These bonds vary on polarity, depending on the relative electronegativity of the 2 atoms.
34
What is one of the most electronegative elements
Oxygen, it attracts shared electrons more strongly than hydrogen.
35
What happens when 2 atoms are so unequal in their attraction for valence electrons
The more electronegative atom completely strips away an electron from its partner.
36
Ions
The 2 oppositely charged atoms after one atoms strips an electron from the other.
37
Cation
A positively charged ion
38
Anion
A negatively charged ion
39
Ionic bond
The attraction of 2 atoms of opposite charge, which doesn't have to be due to the transfer of electrons from that one atom to the other.
40
Ionic compounds (salts)
Compounds formed by ionic bonds
41
Salt crystals
An aggregate of vast numbers of cations and anions bonded by their electrical attraction and arranged in a 3D lattice.
42
What does ion also apply to
Entire molecules that are electrically charged
43
What other factor affects ionic bonds
Environment
44
Why are ionic bonds weaker in water
Each ion is partially shielded by its interactions with water molecules
45
Hydrogen bond
The attraction between a hydrogen and an electronegative atom (usually oxygen or nitrogen).
46
How are hydrogen bonds possible
When a hydrogen atom is covalently bonded to an electronegative atom, the hydrogen atom has a partial positive charge that allows it to be attracted to different electronegative atom nearby.
47
Positively and negatively charged atoms are additionally possible with what bonds
Nonpolar covalent (electrons aren't always evenly distributed)
48
Van der Waals interactions
The not always evenly distributed electrons in non polar covalent bonds that create ever changing regions of positive and negative charge, this allows all atoms and molecules to stick to one another. Individually weak, occur only when atoms and molecules are close together.
49
How can these interactions be powerful
When many occur simultaneously
50
Van der Waals interactions, hydrogen bonds, ionic bonds in water and other weak bonds may forms ______
not only between molecules but also between parts of large molecules such as protein.
51
A molecule consisting of 2 atoms is always what
Linear
52
Shapes are determined by what
The positions of the atoms' orbitals
53
When an atom forms covalent bonds, what happens to the orbitals in the valence shells
They undergo rearrangement
54
How do atoms with valence electrons in s and p orbitals change
The single s and 3 p orbitals form 4 new hybrid orbitals shaped liked identical teardrops extending from the region of the atomic nucleus The the larger ends of the teardrops and connected with lines, a tetrahedron is formed.
55
In water molecules 2 of the hybrid orbitals are shared with what
Hydrogens, resulting in a v shaped molecule.
56
How does the methane molecule have the shape of a completed tetrahedron
All four hybrid orbitals of the carbon atom are shared with hydrogen atoms. The carbon nucleus is at the center, with its 4 covalent bonds radiating to hydrogen nuclei at the corners of the tetrahedron.
57
What does molecular shape determine
How biological molecules recognize and respond to one another with specificity.
58
Chemical reactions
The making and changing of chemical bonds leading to changes in the composition of matter.
59
Reactants
The starting materials
60
Products
What is produced
61
What do coefficients indicate
The number of molecules involved. (2NH)
62
Matter is _______ in a chemical reaction
Conserved. Reactions cannot create or destroy atoms but can only rearrange the electrons among them.
63
Photosynthesis
6 H2O + 6 CO2 -----> C6H12O6 + 6 O2
64
All chemical reactions are
Reversible
65
Opposite 2 headed arrows indicate
The reaction is reversible
66
The greater the concentration of reactant molecules
The more frequently they collude with one another and have an opportunity to react and form products.
67
As products accumulate
Collisions resulting in the reverse reaction become more frequent
68
What happens when eventually the forward and reverse reactions occur at the same rate
The relative concentrations of products and reactants stop changing.
69
Chemical equilibrium
The point at which the reactions offset one another exactly. Reactions are still going on, but with no net effect on the concentrations of reactants and products.
70
What does equilibrium NOT mean
The reactants and products are equal in concentration, it only means their concentrations have stabled at a specific ratio.