2EXAM-HChem Flashcards

(83 cards)

1
Q

___ properties depend on the amount

___ properties depend on type of matter, not the amount

A

Extensive

Intensive

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2
Q

Chemical changes (are/are not) reversible

A

Are not

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3
Q

Changes of state are (physical/chemical)

What does this include

A

Physical

Boiling, melting

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4
Q

Elements are organized in the periodic table by ___ periods and ___ groups

A

7, 18

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5
Q

What is evidence of a chemical reaction

A

Production of heat or light, a color change, the production of a gas, or the formation of a precipitate

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6
Q

____________ describes that mass is conserved during chemical or physical changes. Mass of reactants=Mass of products

A

Conservation of mass

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7
Q

In scientific notation, the base must be…

A

Equal to or greater than 1 and less than 10

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8
Q

What is Avogadro’s number

A

6.022 x 10^23

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9
Q

What is the difference between accuracy and precision

A

Accuracy: describes how a measurement agrees with the correct or accepted value (bullseye)
Precision: describes how a measurement agrees with other values (consistency)

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10
Q

Sig figs contain all of the numbers known for certain plus

A

One estimate

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11
Q
What is the SI unit for:
Mass-
Length-
Time-
Amount of substance-
Temperature-
A
Kilogram
Meter
Second
Mole
Kelvin
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12
Q

How do you convert C to F

How do you convert F to C

A

F=C*9/5 +32

C=(F-32)*5/9

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13
Q

Where are protons and neutrons located

A

The nucleus

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14
Q

The number of neutrons =

A

Mass number-number of protons

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15
Q

What are the four orbital shapes that electrons can occupy

A

S(sphere), p (peanut), d (double peanut), f (flowers)

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16
Q

What is the trend for atomic radius?

What is the trend for ionization energy?

A

Increases left and down

Increases right and up

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17
Q

What is ionization energy

A

The amount of energy required to remove the most loosely bound electron, the valence electron, of an isolated gaseous atom to form a cation

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18
Q

Electrons want to be unpaired until they’re forced to pair

A

Hund’s Rule

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19
Q

When assigning orbitals to electrons, always fill lowest energy first

A

Aufbau’s Principle

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20
Q

What are the rules for electron dot notation

A

No side can have more than two dots because each orbital can only hold two electrons
Each side gets one dot before doubling up

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21
Q

What is a photon

A

A package of energy that travels on transverse waves

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22
Q

The wavelength is between two ___

A

Crests

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23
Q

The amplitude of a wave is…

A

The distance from the middle to the top

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24
Q

Color of light is established by _____

A

Wavelength

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25
_________ is how many waves pass a point in 1 second
Frequency
26
Frequency is represented by a __
V
27
What are units for frequency
Wps, cps, hertz, s^-1
28
_____ travel at the speed of light
Electrons
29
electrons start in (lowest/highest) possible energy
Lowest (ground state)
30
Increasing wavelength ____ energy
Decreases
31
Ionic bonding involves the ____ of electrons
Transfer
32
What are the two types of covalent bonding
Polar and nonpolar
33
What is electronegativity
A measure of the tendency of an atom to attract a bonding pair of electrons
34
How do you calculate N,A,S numbers for atoms/polyatomic ions
N is needed (they all need 8 expect H needs 2, Be needs 4, Boron needs 6) A is available, use valence electron number and look at charge S is N-A. Divide by 2 and put that number of lone pairs on the central atom
35
What are the two conditions that will result in a molecule being polar
One or more lone pairs on center atom (dipoles will angle) | If you have different atoms connected to your center (different electronegativities)
36
_____ are neutral | _____ have a charge
Atoms | Ions
37
All elements want to have the electron arrangement of the ______ noble gas
Nearest
38
D-block metals form ___
Cations
39
Oxyacids contain __,__, and a third element
H, O
40
When you're naming compounds, use the full name of __ and __
Sulfur, phosphorus
41
How do you do empirical formula
Divide percentage by atomic mass, divide all solutions by smallest number, get whole numbers by multiplying ALL RESULTS
42
How do you find the molecular formula
Divide the total mass by the mass present in the compound | Use that as the subscript
43
Empirical formula is _____ | Molecular formula is ____
Simplest | Actual
44
What are the 5 types of equations
``` Synthesis Decomposition Single Displacement Double displacement Combustion ```
45
Which is NOT a sign that a double replacement reaction will occur Light is emitted, ppt is produced, H20 is formed, gas is formed
Light is emitted
46
The reaction Li+02--->Li20 is ...
Synthesis and Combustion
47
When you add an acid to a base, the solution ______________ | If you add a base to an acid, it ______
Stays pink | Flashes pink
48
How do you find the limiting reactant
Convert grams of the reactant to grams of the product | Whichever is less is the limiting
49
What must be the units for gas laws
Pressure-atm Volume- l Temp- K
50
If you're using the ideal gas law for a wet/dry gas, make sure you have the correct ____ by using Dalton's law
Pressure (subtract or add given water vapor pressure
51
The acid ____ the proton while the base _____ it
Donates/accepts
52
The conjugate base goes with the _______
Acid
53
What are the rules for naming acids and bases
``` Normal: ic +1: per_ic -1: _ous -2:hypo_ous (Look at subscript) ```
54
When writing rate laws, don't forget the _
K
55
What is the unit for k
M^-overall order -1 s^-1
56
The rate determining step is the ___ step
Slowest
57
LeChatelier's Principle says that
When you put a stress on a reaction, it will respond to relieve the stress Also called the equilibrium law
58
Adding a catalyst to a reaction shifts the reaction...
NOT AT ALL | NO SHIFT
59
Decreasing the volume makes the reaction shift towards
The side with less moles
60
Decreasing volume=
Increasing pressure
61
What is entropy
Measures the degree of disorder
62
All objects have a tendency to go towards _delta H and _delta S
-,+ | Less energy, more disorder
63
Endothermic reactions ____ heat and the energy is in the ___ | Exothermic reactions _____ heat and the energy is in the ____
Absorb, reactant | Release, product
64
What is enthalpy
Change in heat (delta H)
65
What is Hess's Law of Intermediates
The heat of formation of the steps must add up to the total
66
What is Hess's law of summation
Heat of reaction=sum of heat of formation of products times moles-sum of heat of formation of reactants times moles
67
Delta Hf values for elements are 0 | Why
They are naturally occurring and no heat is absorbed
68
In Gibbs, temperature must be in _____
Kelvin
69
What element goes in the center for Lewis structure
Least electronegative
70
When doing Lewis structure, make sure..
Electrons drawn equals A number
71
Mr Cousineau serves ham sandwiches according to the following equation 1Ham+2Bread+1Cheese-->1Sandwich If Mr. C buys 24 slices of bread, 14 slices of ham, and 16 slices of cheese, which ingredient will be the limiting reactant? (How do you know)
The bread Divide each of the amount of ingredients you buy by the number of ingredients per one sandwich, whichever is the least (bread) is the limiting reactant
72
Nomenclature | Describe the rules for each situation
Binary ionic- cation unchanged and then the anion stem+ide D-block ionic- cation unchanged, Roman numeral, anion stem+ide Covalent- right of staircase cation, use prefixes di, tri, tetra, penta Binary acid- hydro_____ic acid Oxyacid- compare to polyatomic -ate form. Use per___ic, ___ic, ___ous, hypo___ous
73
If you need the mass of one molecule of something, what do you do
Convert molecules to moles and moles to grams
74
One mole is different from one _____
Molecule
75
How would you find the mass of one molecule of C8H18
Convert molecules to moles using Avogrado's number and then convert moles to grams
76
Is wood heterogenous or homogenous
Heterogenous
77
Flammability is a ____ property
Chemical
78
Conductor of heat is a ___ property
Physical
79
Melting is a ___ property
Physical
80
Dissolving readily in water | Physical or chemical
Physical
81
Dissolving salt in water is a _____ change
Physical
82
Boiling is a ______ property
Physical
83
Density is an ___ property
Intensive