APCHEM Chemical Equilibrium Flashcards

(23 cards)

0
Q

Equilibrium law

A

The concentration of all the products multiplied together divided by the reactants multiplied together. (Equals Kc)

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1
Q

Dynamic equilibrium

A

A chemical process that is going in the forward and in the reverse directions at the same rate, leaving the concentration of the reactants and products constant

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2
Q

What two cases will a substance not be included in the equilibrium law equation?

A

When it’s a Pure liquid or a solid

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3
Q

More reactants/products rules

A

Kc is greater than 10^10=mostly product
Kc is less than 10^-10=mostly reactant
Kc=1 the there are approximately equal amounts of products and reactants

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4
Q

Rules of spontaneity

A

Kc>1 spontaneous (products form when reactants are mixed without help)
Kc<1 nonspontaneous (reaction needs help to occur)

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5
Q

Three principles of Q

A

Q=Kc the reaction is at EQ
Q<Kc>Kc the reaction will go in the reverse direction making more reactants to reach equilibrium</Kc>

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6
Q

What is meant by chemical equilibrium ?

A

The reactant and product concentration are constant

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7
Q

What is an equilibrium constant

A

Kc (products/reactants)

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8
Q

Formula for the relationship between Kp and Kc

A

Kp=Kc(RT)^change in mol

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9
Q

What does Ksp mean?

A

How much solute will dissolve within a solution

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10
Q

Saturated solution

A

EQ solution where the max amount of solute has been dissolved and there’s extra solid in the solution

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11
Q

What does large and small Ksp mean?

A

Large- ionic solid is very soluble

Small- ionic solid not very soluble

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12
Q

Solubility

A

The max amount of solid that can be dissolved in a solvent g/L

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13
Q

Molar solubility

A

Solubility is units mol/L

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14
Q

Solubility constant (Ksp)

A

Ratio that expresses the magnitude in the difference between the reactant concentration and the ionic solute.

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15
Q

What is X?

A

Molar solubility mol/L

16
Q

Le Chatelier’s Principle

A

If a system at equilibrium is disturbed by a change in temperature pressure or concentration, the system will shift to counteract the effect of the disturbance

17
Q

Add reactant-

Add product-

18
Q

Remove reactant-

Remove product-

19
Q

To Reduce pressure

A

Shift to the side with fewer moles

20
Q

To Increase pressure

A

Shift to the side with more moles

21
Q

Endothermic increase in T

Endothermic decrease in T

A

Increase K right

Decrease K left

22
Q

Exothermic increase in T

Exothermic decrease in T

A

Decrease K left

Increase K right