Chemistry - Ch 13 Flashcards

(38 cards)

0
Q

Hydration

A

interactions between solute/solvent when the solvent is water

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1
Q

Solvation

A

Interactions between solute and solvent molecules

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2
Q

Entropy

A

degree of randomness in the system (AKA disorder); thermodynamic quantity

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3
Q

Hydrates

A

salt and water combined in definite proportions, like FeCl3 + 6H2O

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4
Q

Water of hydration

A

water associated with hydrates

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5
Q

Crystallization

A

opposite of solution process; solute particle reattaches to solid

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6
Q

Saturated

A

solution in equilibrium with undissolved solute

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7
Q

Solubility

A

Amount of solute needed to form a saturated solution in a given quantity of solvent

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8
Q

Unsaturated

A

if less solute is dissolved than is needed to form a saturated solution

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9
Q

Supersaturated

A

solutions with a greater amount of solute than needed to form a saturated solution

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10
Q

Miscible

A

pairs of liquids (ex. acetone & water) that mix in all proportions

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11
Q

Immiscible

A

Pairs of liquids that do not dissolve in one another

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12
Q

Henry’s Law

A

relationship between pressure and the solubility of a gas; Sg (solubility of gas in solution) = k (Constant) times Pg (partial pressure of the gas over the solution); K is different for each solute-solvent pair

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13
Q

Mass percentage

A

(Mass of component in solution divided by total mass of solution) x 100%

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14
Q

Parts per million (ppm)

A

how concentrations of very dilute solution are expressed

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15
Q

Mole fraction

A

moles of component divided by total moles of all components

16
Q

Molality (m)

A

number of moles of solute divided by kilograms of solvent

17
Q

Colligative properties (“depending on the collection”)

A

properties that depend on the collective effect of the number of solute particles

18
Q

Raoult’s Law

A

partial pressure is exerted by solvent vapor above a solution (P subscript A) = the product of the mole fraction of the solvent in the solution (X subscript A) times the vapor pressure of the pure solvent (P degree subscript A)

19
Q

Ideal solution

A

obeys Raoult’s Law

20
Q

Molal boiling-point-elevation constant

A

(Kb) a constant characteristic of a particular solvent that gives the increase in boiling point as a function of solution molality

21
Q

Molal freezing-point-depression

A

(Kf) a constant characteristic of a particular solvent that gives the decrease in freezing point as a function of solution molality

22
Q

Osmosis

A

Net movement of solvent is always toward the solution with the higher solute concentration

23
Q

Osmotic pressure

A

pressure required to prevent osmosis by pure solvent

24
Isotonic
if 2 solutions of identical osmotic pressure are separate by a semipermeable membrane, no osmosis will occur
25
Hypotonic
if one solution is of lower osmotic pressure, it is _______ with respect to the more concentrated solution
26
Hypertonic
the more concentrated solution is ________ with respect to the dilute solution
27
Crenation
osmosis causing a cell to shrivel
28
Hemolysis
Osmosis causing a cell to rupture
29
Active transport
in some cases, substances must be moved across the cell membrane from an area of low concentration to one of high concentration; not spontaneous
30
Colloidal dispersions (colloids)
mixtures containing particles larger than normal solutes but small enough to remain suspended in the dispersing medium
31
Tyndall Effect
scattering of light by colloidal particles
32
Hydrophilic colloid
water-loving
33
Hydrophobic colloid
Water-fearing
34
Adsorption
to adhere to a surface
35
Emulsion
suspension of one liquid in another
36
Coagulation
process of enlarging colloidal particles
37
Dialysis
using semipermeable membranes to separate ions from colloidal particles