labster/ quiz org chem midterm Flashcards

1
Q

you can see the 2d structure of two hydrocarbons. can you spot the difference between them

A

the bonds are different

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2
Q

alkane with 6 carbon atoms

A

hexane

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3
Q

one of the major constituent of gasoline

A

hexane

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4
Q

correct ending for a hydrocarbon with no or double triple bond

A

pentane

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5
Q

used for alknaes, single bonds only

A

-ane

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6
Q

which of this the carbon name for hydrocarbon with the carbons, and a double bond

A

ethene

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7
Q

which compound is being shown here on the holo-table right now?

A

but-7-ene

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8
Q

which compound is not present

A

ethane

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9
Q

is best at getting a quick of the number of each element in the compound?

A

molecular formula

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10
Q

which type of hydrocarbon will not react with bromine

A

alkanes

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11
Q

which of the following unknown compound do you think is saturated hydrocarbon?

A

unknown compound 2

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12
Q

do you know which role the double bond plays in the electrophilic

A

nucleophile

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13
Q

for these intermeditae, it seems afew carbocations have formed. which is the least stable type of carbocations?

A

methyl cation (cat-ion)

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14
Q

identify the connect combination of major minor products

A

major 2- bromobutane; minor 1-bromobutane

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15
Q

what is the main differenece the displayed and the partially condensed formula?

A

some bonds are implied in the partially condensed. whereas all bonds are shown in the displayed formula

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16
Q

what do you think the core rules for the skeletal type?

A

carbons are implied at the line corners and ending and the hydrogens are implied in general

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17
Q

Which type of isomerism does not involve
chirality?

A

Constitutional isomerism

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18
Q

What instrument is used to measure optical
activity?

A

Polarimeter

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19
Q

What does it mean when a molecule is achiral?

A

It is superposable on its mirror image

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20
Q

What is the basis for assigning priority in the R/S
system?

A

Atomic number of atoms attached to the
stereocenter

21
Q

A dextrorotatory compound rotates planepolarized
light:

22
Q

Which of the following is not a characteristic of
enantiomers?

A

They have different boiling points

23
Q

Why do enantiomers have different biological
effects?

A

They interact differently with
chiral biological molecules

24
Q

What is a meso compound

A

A compound with
multiple stereocenters but no chirali

25
Which of the following conditions must be met for a molecule to exhibit optical activity
It must be chiral
26
If the priority order of groups is read in a clockwise direction, what is the configuration?
R
27
Which biological molecules are often chiral?
All of the above
28
Which of the following is a characteristic of enantiomers?
All of the above
29
What is the most common cause of chirality in organic molecules?
Presence of a carbon with four different groups attached
30
Which of the following is an example of diastereomers?
cis- and trans-1,2-dichloroethene
31
How can one separate a racemic mixture into its individual enantiomers
Using a chiral resolving agent
32
What is the effect of (R)-naproxen in the body?
Liver toxicity
33
How many stereoisomers are possible for a molecule with two stereocenters
4
34
What is the relationship between (R)-2-butanol and (S)-2-butanol?
Enantiomers
35
The R/S system is used to ________.
Differentiate between enantiomers
36
The formula for calculating the maximum number of stereoisomers for a molecule with n stereocenters is:
2ⁿ
37
what happens when plane-polarized light passes through an optically active compound?
It is rotated either clockwise or counterclockwise
38
Why do biological systems often use only one enantiomer of a chiral compound
Enzymes are chiral and selective
39
The configuration of a molecule can be determined using
Both a and c
40
What does "chiral" mean in chemistry?
A molecule that is not superposable on its mirror image
41
How many stereoisomers are possible for a molecule with three stereocenters?
8
42
How do diastereomers differ from enantiomers?
Diastereomers are nonsuperposable and not mirror images
43
A racemic mixture contains:
Equal amounts of R and S enantiomers
44
HCI4
Hydrochloride Acid
45
Which of the following compounds is most likely to be chiral?
2-Butanol
46
Soduim hydroxide
NaOH
47
The solution has turned red. What do you think result means?
The Unknown compound contains a primary aromatic amine
48
c=o
oxo
49
cho
formyl