Chem test 1-2 Flashcards

(49 cards)

1
Q

ethers - H bonding

A

cannot be the H bonding donor, no H bonding within themselves,

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2
Q

R-O-R

A

ether

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3
Q

low boiling point

A

ether

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4
Q

common ether naming

A

di alkyl ether

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5
Q

CH3-O-CH3

A

dimethyl ether

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6
Q

alkoxy group

A

It’s just any alkyl group bonded to an oxygen. R-O-R

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7
Q

CH3-O

A

methoxy

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8
Q

when naming alkoxy

A

first R is the smaller alkyl group, then oxy, then the larger alkane name

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9
Q

CH3CH2-O-CH3 name…

A

methoxy ethane

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10
Q

only consider iso goes..

A

alphabetically

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11
Q

anisol (ana at ochsha)

A

benzene with OCH3 on very top

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12
Q

in dehydration reaction, you need to take the H from (Don’t dehydrate your neighbor)

A

the C NOT attached to the OH group -

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13
Q

oxidation is…(definition)

A

increase in the number of C-O bonds, or decreases the number of C-H bonds

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14
Q

in oxidation, you take the H from (give your neighbor oxygen)

A

the C attached to the O

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15
Q

in dehydration of alcohol, the product is

A

H20

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16
Q

for dehydration of alcohol, all you are doing is..

A

getting rid of the OH, and getting rid of one H on either of the adjacent carbons attached to the OH.

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17
Q

aldehyde functional group (chew the hyde)

A

CHO - the O can be a double bond

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18
Q

ketone functional group

A

C=O

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19
Q

you can only oxidize

A

primary and secondary alcohols

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20
Q

you cannot oxidize

A

tertiary alcohols - there is no H to remove - it’s just a C in the middle with no Hs attached

21
Q

benzene w/ OH attached is called…(pheral w/ benz)

22
Q

phenyl

A

is just a benzene as a side chain minus one H - C6H5

23
Q

benzyl (benzyl my methyl)

A

a benzene attached to a CH2

24
Q

common name example

A

ethyl alcohol

25
carbonyl group (carbunkle gets double and single)
just a carbon attached to O with double bond C=O
26
organic oxidation
increases number of O bonds or decreases number of H bonds
27
organic reduction (reduce the O!)
decreases number of O bonds or increases number of H bonds
28
ketones (key key key it twice)
C-C-C=O
29
when oxidized, primary alcohols become...
aldhydes
30
when oxidized, secondary alcohols become...
ketones
31
when oxidized, tertiary alcohols become...
no reaction - no H to donate
32
to name ethers...
look at the branches on either side of the O, and then add ether to the end. ie - CH3 - O - CH3 is dimethyl ether
33
alkoxy group
an OR group in a chain, ie - CH3CH2O is ethoxy - but it will be part of a larger chain
34
when oxidized, thiols become...
disulfides
35
amine functional group
NH2
36
amide functional group
NH2 = O
37
thiols functional group
SH
38
disulfide functional group
R-S-S-R
39
Alkylhalides functional group
carbon halide bond
40
geometric isomers (bondage geometry)
same formula, but different bond for example
41
structural isomers (your sis is structured)
cis and trans
42
bond rotation of alkane
sigma bonds, rotate freely - conformation
43
bond rotation alkene and alkyne
none
44
bond angle alkane (kane on the radio)
109.5
45
bond angle alkene (keen for 120 min)
120
46
bond angle for alkyne (kyna is fast)
180
47
combustion of alkene (poodle)
Cn2n + (3n/2) O2 = n CO2 + n H2O
48
combustion of alkane
CnH2n+2 + (3n+1)/2 O2 = n CO2 + (n+1) H2O
49
combustion of alkyne (kyne minus 2)
CnH2n-2 + (3n-1)/2 O2 = n CO2 + n H2O